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Nowadays, transition metal\u2010catalyzed carbonylation represents a pivotal synthetic approach for the generation of carbonyl\u2010containing molecules. Among the known catalysts for these transformations, non \u2010noble metal\u2010based systems have garnered increasing interest in recent years due to their substantial advantages, including wide availability, low cost, and low toxicity. In this review, we have summarized and discussed original and recent developments in iron\u2010catalyzed carbonylative transformations, wherein CO is utilized as the C\n                    <jats:sub>1<\/jats:sub>\n                    feedstock.\n                  <\/jats:p>","DOI":"10.1002\/anie.202512346","type":"journal-article","created":{"date-parts":[[2025,8,11]],"date-time":"2025-08-11T06:18:45Z","timestamp":1754893125000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Iron\u2010Catalyzed Carbonylation Reactions with Carbon Monoxide"],"prefix":"10.1002","volume":"64","author":[{"given":"Kangkang","family":"Sun","sequence":"first","affiliation":[{"name":"State Key Laboratory of Microbial Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials Jiangsu Key Laboratory of New Power Batteries School of Chemistry and Materials Science Nanjing Normal University  Nanjing 210023 P.R. 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