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However, there is a lack of high\u2010performance photocatalysts. Herein, we report a nanoflower\u2010like bimetallic porphyrin metal\u2013organic framework superstructure (Cu\u2010TCPP(Co)\u2010NF, TCPP\u00a0=\u00a0tetrakis(4\u2010carboxyphenyl)porphyrin) as an efficient NitRR&amp;CRR photocatalyst for urea production. Systematical investigations have revealed that the Cu and Co centers serve as the active sites for driving NitRR and CRR, respectively. The high pore volumes of nanoflower architecture can improve the light adsorption, promote the reactant enrichment, and intermediate generation. Consequently, the C\u2013N coupling process over Cu\u2010TCPP(Co)\u2010NF is facilitated with reduced energy barriers and inhibited side reactions, resulting in an unprecedent urea yield of 2459.8\u00a0\u00b5g h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    in the absence of sacrificial agents. This study provides new insights into the design of advanced photocatalysts for urea synthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.202512615","type":"journal-article","created":{"date-parts":[[2025,8,19]],"date-time":"2025-08-19T13:42:58Z","timestamp":1755610978000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Photocatalytic Co\u2010Reduction of CO\n                    <sub>2<\/sub>\n                    and Nitrate over Porphyrin Metal\u2013Organic Frameworks: Dual Atomic Active Site and Nanostructure Synergy Enhances C\u2013N Coupling for Urea Production"],"prefix":"10.1002","volume":"64","author":[{"given":"Tong","family":"Bao","sequence":"first","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chencheng","family":"Tang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunuo","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yin","family":"Bi","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chaoqi","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yamin","family":"Xi","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingying","family":"Zou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"},{"name":"State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE East China Normal University  Shanghai 200062 P.R. China"},{"name":"Shanghai Frontiers Science Center of Molecule Intelligent Syntheses School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3707-0785","authenticated-orcid":false,"given":"Chengzhong","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P.R. China"},{"name":"State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE East China Normal University  Shanghai 200062 P.R. China"},{"name":"Australian Institute for Bioengineering and Nanotechnology The University of Queensland  Brisbane QLD 4072 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,8,19]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202412031"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-56307-w"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-021-00741-3"},{"key":"e_1_2_7_4_1","first-page":"46","volume":"5","author":"Wang L.","year":"2025","journal-title":"Chem. 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