{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T19:11:22Z","timestamp":1785870682381,"version":"3.56.0"},"reference-count":41,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2025,9,1]],"date-time":"2025-09-01T00:00:00Z","timestamp":1756684800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22103054 22173066"],"award-info":[{"award-number":["22103054 22173066"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20211316"],"award-info":[{"award-number":["BK20211316"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20211316"],"award-info":[{"award-number":["BK20211316"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20230065"],"award-info":[{"award-number":["BK20230065"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010881","name":"Suzhou Municipal Science and Technology Bureau","doi-asserted-by":"publisher","award":["SYG202125"],"award-info":[{"award-number":["SYG202125"]}],"id":[{"id":"10.13039\/501100010881","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20211316"],"award-info":[{"award-number":["BK20211316"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20211316"],"award-info":[{"award-number":["BK20211316"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20230065"],"award-info":[{"award-number":["BK20230065"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,10,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Designing unique electrocatalysts that utilizes carbon dioxide reduction reaction (CO<jats:sub>2<\/jats:sub>RR) for real applications is highly appreciated, yet still suffers from low selectivity, stability, and compatibility. Herein, we first report a new two\u2010dimensional metastable\u2010phase transparent conducting oxide: 1T phase indium tin oxide (m\u2010ITOs) with the space group of P\u22123m1 (164), which is totally different from that of the stable cubic phase ITO (Ia\u22123 (206)). The internal indium tin catalytic pairs in m\u2010ITOs trigger the strong electronic coupling, move up the <jats:italic>p<\/jats:italic>\u2010band center, and stabilize the adsorption of HCOO* for increased formate production. In a liquid\u2010phase flow cell, m\u2010ITOs exhibit a high CO<jats:sub>2<\/jats:sub>RR electrocatalytic performance with the formate selectivity up to 93\u00a0\u00b1\u00a01.9% (83\u00a0\u00b1\u00a03.1% for c\u2010SnInO<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic> and 74\u00a0\u00b1\u00a00.6% for In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/SnO<jats:sub>2<\/jats:sub>) and remains 97% (58% for c\u2010SnInO<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic> and 60% for In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/SnO<jats:sub>2<\/jats:sub>) of catalytic activity after a 120,000\u00a0s stability test. Owing to the efficient formate formation with directly using the absorbed CO<jats:sub>2<\/jats:sub> in water and high transparent property, m\u2010ITOs exhibit excellent antifouling behavior of inhibiting <jats:italic>Chlorella<\/jats:italic> growth without reducing the transparency of itself, encouraging a promising application of observation windows in water.<\/jats:p>","DOI":"10.1002\/anie.202513052","type":"journal-article","created":{"date-parts":[[2025,9,2]],"date-time":"2025-09-02T05:43:15Z","timestamp":1756791795000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["A New Phase Indium Tin Oxide (ITO) Activated Selective CO<sub>2<\/sub> Reduction into Formate for Underwater Antifouling Glass"],"prefix":"10.1002","volume":"64","author":[{"given":"Jinxin","family":"Chen","sequence":"first","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"},{"name":"College of Chemistry Chemical Engineering and Materials Science Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenxiang","family":"Zhu","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengling","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Yang","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengjie","family":"Ma","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Penghao","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongdong","family":"Gao","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qun","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei\u2010Hsiang","family":"Huang","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Research Centre  101 Hsin\u2010Ann Road Hsinchu 30076 Taiwan"},{"name":"Sustainable Electrochemical Energy Development (SEED) Center National Taiwan University of Science and Technology  Taipei 106 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chih\u2010Wen","family":"Pao","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Research Centre  101 Hsin\u2010Ann Road Hsinchu 30076 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiwei","family":"Hu","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institute for Chemical Physics of Solids  N\u00f6thnitzer Street 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhui","family":"Kang","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingwang","family":"Shao","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9858-0458","authenticated-orcid":false,"given":"Qi","family":"Shao","sequence":"additional","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science Soochow University  Jiangsu 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5470"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202211396"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00360"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200350v"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202000936"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2023.101755"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201001215"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr030669z"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.10.002"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-26336-2"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE03351H"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218924"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2015.08.085"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889801002242"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2020.155857"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201701531"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c05520"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE03610F"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014655"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0909049505012719"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04873"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201713003"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50211a080"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60252a004"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201612194"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00402"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303889"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402070"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00788-1"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202309376"},{"key":"e_1_2_7_31_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202511132","volume":"64","author":"Li J.\u2010Y.","year":"2025","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b13786"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-021-00974-5"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2020.04.022"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2015.12.030"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803514"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313858"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11126"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202101956"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EN00829B"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsabm.8b00319"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202513052","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,18]],"date-time":"2025-10-18T17:13:46Z","timestamp":1760807626000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202513052"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9]]},"references-count":41,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2025,10,20]]}},"alternative-id":["10.1002\/anie.202513052"],"URL":"https:\/\/doi.org\/10.1002\/anie.202513052","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9]]},"assertion":[{"value":"2025-06-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-08-21","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202513052"}}