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With this research, we developed an RTP film (Cell\u2010Lig) through ethanol\u2010induced phase transition, achieving solid film formation within 1 s from ionic liquid (1\u2010butyl\u20103\u2010methylimidazolium chloride, [Bmim]Cl) solutions of cellulose and lignin. The phase transition also generated a confined rigid environment for Cell\u2010Lig, activating thickness\u2010 and temperature\u2010dependent green RTP emission from the incorporated lignin. Furthermore, red afterglow emission using an energy transfer mechanism was realized by incorporating rhodamine B (RhB). The inherent photothermal activity of lignin endowed Cell\u2010Lig with easy recyclability using light\u2010controlled phase transitions. Under irradiation, photothermal evaporation of residual ethanol triggered liquefaction (solid\u2010to\u2010liquid transition), while ethanol reintroduction facilitated instantaneous hardening. Remarkably, the initial RTP performance was maintained over six recycling cycles. Capitalizing on these attributes, Cell\u2010Lig was successfully used for advanced coating and security applications.<\/jats:p>","DOI":"10.1002\/anie.202513113","type":"journal-article","created":{"date-parts":[[2025,8,19]],"date-time":"2025-08-19T12:31:22Z","timestamp":1755606682000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Convenient Production of Photothermal Recycling Phosphorescent Materials from Cellulose and Lignin"],"prefix":"10.1002","volume":"64","author":[{"given":"Ruixia","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Utilization of Woody Oil Resource Northeast Forestry University  Harbin 150040 P.R. China"},{"name":"Key Laboratory of Bio\u2010based Material Science and Technology of Ministry of Education Northeast Forestry University  Harbin 150040 P.R. 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