{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T15:22:53Z","timestamp":1790263373690,"version":"4.1.0"},"reference-count":61,"publisher":"Wiley","issue":"46","license":[{"start":{"date-parts":[[2025,9,25]],"date-time":"2025-09-25T00:00:00Z","timestamp":1758758400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"},{"start":{"date-parts":[[2025,9,25]],"date-time":"2025-09-25T00:00:00Z","timestamp":1758758400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,11,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Porous adsorbents have emerged as leading materials for carbon capture, where pressure\u2010controlled regeneration offers a key advantage over energy\u2010demanding temperature swing adsorption. Flexible metal\u2010organic frameworks (MOFs) comprised of pillared linkers are proposed to meet this need due to the unique ability to adjust their pores to maximize host\u2010guest interactions. However, many pillared MOFs show structural collapse following activation. We highlight a new approach to constructing pillared MOFs which retain their porosity upon activation, while also showing flexibility and selective gas adsorption. Two different MOFs were formed using cubane\u20101,4\u2010dicarboxylate (cdc) as a pillar linking zinc triazolate sheets, [Zn\n                    <jats:sub>2<\/jats:sub>\n                    (trz)\n                    <jats:sub>2<\/jats:sub>\n                    (cdc)] and [Zn\n                    <jats:sub>2<\/jats:sub>\n                    (trz)\n                    <jats:sub>2<\/jats:sub>\n                    (Br\u2010cdc)], and their structural framework dynamics investigated using advanced characterization techniques. In situ X\u2010ray powder diffraction performed in parallel with gas adsorption experiments revealed specific, reversible structural transformations between a narrow pore and open pore phase of the MOFs. These new MOFs reveal a high enthalpy of CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption, driven by interesting network flexibility previously unobserved in the collapsed benzene\u20101,4\u2010dicarboxylate analogue. A combination of experimental techniques and in silico calculations revealed that the phase transformations are governed by local coordination flexibility around the open\u2010metal site available in [Zn\n                    <jats:sub>2<\/jats:sub>\n                    (trz)\n                    <jats:sub>2<\/jats:sub>\n                    (cdc)].\n                  <\/jats:p>","DOI":"10.1002\/anie.202513319","type":"journal-article","created":{"date-parts":[[2025,9,25]],"date-time":"2025-09-25T09:56:57Z","timestamp":1758794217000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Restoring Porosity and Uncovering Flexibility in Pillared 3D\u2010Linker Metal\u2010Organic Frameworks"],"prefix":"10.1002","volume":"64","author":[{"given":"Sophie A.","family":"Booth","sequence":"first","affiliation":[{"name":"School of Chemistry University of New South Wales  Kensington New South Wales 2052 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Volodymyr","family":"Bon","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Technische Universit\u00e4t Dresden  Dresden 01062 Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Connor W.","family":"Edwards","sequence":"additional","affiliation":[{"name":"School of Physics Chemistry and Earth Sciences University of South Australia  Adelaide South Australia 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G. Paul","family":"Savage","sequence":"additional","affiliation":[{"name":"Commonwealth Scientific and Industrial Research Organisation  Clayton Victoria 3168 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jack D.","family":"Evans","sequence":"additional","affiliation":[{"name":"School of Physics Chemistry and Earth Sciences University of South Australia  Adelaide South Australia 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan","family":"Kaskel","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Technische Universit\u00e4t Dresden  Dresden 01062 Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7672-9795","authenticated-orcid":false,"given":"Lauren K.","family":"Macreadie","sequence":"additional","affiliation":[{"name":"School of Chemistry University of New South Wales  Kensington New South Wales 2052 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,25]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202307478"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2RA07940B"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scca.2023.100012"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.4c04212"},{"key":"e_1_2_8_5_1","unstructured":"C. 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