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Herein, we demonstrate that the introduction of electroactive chelating groups can significantly improve both the capacity and cycling stability of p\u2010type triphenylamine derivative\u2010based electrodes. The electroactive chelating groups promote a higher proportion of electroactive sites within the cathode material. The combined in\/ex situ spectroscopic analysis and theoretical investigations show that electroactive chelating groups facilitate the formation of stable zinc\u2010supramolecular network, which effectively mitigates the dissolution of electrode materials and the decomposition of the aqueous electrolyte during cycling. The as\u2010synthesized poly(1,4\u2010naphthoquinone\u20101,3,5\u2010tri(4\u2010aminophenyl)benzene) exhibits a high reversible capacity of 311 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 50\u00a0mA\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and superior rate performance (199 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 10 A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) in aqueous electrolyte. Moreover, it demonstrates excellent stability, retaining 83% to 96% of its capacity over 5000 cycles in various aqueous electrolytes, representing a new record for p\u2010type and bipolar\u2010type organic electrode materials. This work provides valuable insights into the design of organic electrode materials for high\u2010performance ZIBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202513842","type":"journal-article","created":{"date-parts":[[2025,11,3]],"date-time":"2025-11-03T07:47:56Z","timestamp":1762156076000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Electroactive Chelating Groups Enable High\u2010Performance Aqueous Zinc\u2010Organic Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Jin","family":"Zhou","sequence":"first","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongbin","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Massachusetts Institute of Technology  Cambridge MA 02139 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peifang","family":"Guo","sequence":"additional","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jihuang","family":"Jiao","sequence":"additional","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufei","family":"He","sequence":"additional","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiangqiang","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingyu","family":"Ding","sequence":"additional","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Da","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7841-8058","authenticated-orcid":false,"given":"Ju","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Massachusetts Institute of Technology  Cambridge MA 02139 USA"},{"name":"Department of Nuclear Science and Engineering Massachusetts Institute of Technology  Cambridge MA 02139 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Renbing","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Smart Materials and Future Energy State Key Laboratory of Coatings for Advanced Equipment Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,11,2]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE02526J"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00349E"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/smm2.1110"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00929K"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2024.235515"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.156870"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202204005"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202401049"},{"key":"e_1_2_8_9_1","author":"Zhang Q.","year":"2024","journal-title":"Adv. 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