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In this work, we assess the \u201chard\u201d and \u201csoft\u201d Lewis acid characteristics of Sn<jats:sup>2+<\/jats:sup> and Pb<jats:sup>2+<\/jats:sup> cations as a strategy to modulate the chemical environment of these metal\u2010containing species in mixed\u2010metal tin\u2013lead perovskite precursor solutions. We observe enhanced simultaneous access to both metal centres upon adding compounds with functional groups suggested by the hard\u2013soft acid\u2013base principle. Theoretical calculations suggest that the hard base carboxyl group preferentially interacts with Sn<jats:sup>2+<\/jats:sup>\u2010based species, while the softer base thiol group also targets Pb<jats:sup>2+<\/jats:sup>\u2010based species. 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