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The compounds crystallize at ambient temperature and feature P\u2550E double bonds, as confirmed by structural and computational studies. Compounds\n                    <jats:bold>2<\/jats:bold>\n                    \u2013\n                    <jats:bold>4<\/jats:bold>\n                    undergo [4+2] cycloaddition with 2,3\u2010dimethyl\u20101,3\u2010butadiene to furnish six\u2010membered heterocyclic products, demonstrating their \u03c0\u2010bond reactivity. Compound\n                    <jats:bold>3<\/jats:bold>\n                    reacts with mesityl azide to afford a P(V) compound. Additionally,\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    are capable of oxidative cleavage of O\u2500H and N\u2500H bonds in H\n                    <jats:sub>2<\/jats:sub>\n                    O and NH\n                    <jats:sub>3<\/jats:sub>\n                    , respectively. Furthermore,\n                    <jats:bold>2<\/jats:bold>\n                    \u2013\n                    <jats:bold>4<\/jats:bold>\n                    can be one\u2010electron reduced to their corresponding radical anion salts, which are unprecedented radical anions of pnictinidene chalcogenides isolable in the condensed phase.\n                  <\/jats:p>","DOI":"10.1002\/anie.202514521","type":"journal-article","created":{"date-parts":[[2025,8,28]],"date-time":"2025-08-28T04:52:26Z","timestamp":1756356746000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Isolable Arylphosphinidene Chalcogenides and their Radical Anions"],"prefix":"10.1002","volume":"64","author":[{"given":"Xinyi","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education Guangdong Basic Research Center of Excellence for Functional Molecular Engineering School of Chemistry IGCME Sun Yat\u2010sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yizhen","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education Guangdong Basic Research Center of Excellence for Functional Molecular Engineering School of Chemistry IGCME Sun Yat\u2010sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yushuang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education Guangdong Basic Research Center of Excellence for Functional Molecular Engineering School of Chemistry IGCME Sun Yat\u2010sen University  Guangzhou 510275 China"},{"name":"School of Chemistry and Environment Jiaying University  Meizhou 514015 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Xu","sequence":"additional","affiliation":[{"name":"Jiangsu Key Lab of Data Engineering and Knowledge Service Key Laboratory of Data Intelligence and Interdisciplinary Innovation Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6972-2197","authenticated-orcid":false,"given":"Gengwen","family":"Tan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education Guangdong Basic Research Center of Excellence for Functional Molecular Engineering School of Chemistry IGCME Sun Yat\u2010sen University  Guangzhou 510275 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