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Confinement within the framework of zeotype materials distinguishes the function of carbenium ions as catalytic centers in various chemical processes. A selective and reversible deprotonation event of benzenium ions built in H\u2010ZSM\u20105 during methanol conversion was observed by experiment and theory as a result of CD\n                    <jats:sub>3<\/jats:sub>\n                    CN dosage, denoting their higher acid reactivity compared to the cyclopentenyl cations, which undergo deprotonation only in presence of pyridine. This study uncovers the inverse relationship between the acid reactivity of carbenium ions of different nature and their stability in the surface\u2010bound state.\n                  <\/jats:p>","DOI":"10.1002\/anie.202514759","type":"journal-article","created":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T23:38:56Z","timestamp":1759793936000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Influence of the Acid Reactivity of Carbenium Ions in Zeolites on the Methanol\u2010to\u2010Olefins Process"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5925-2817","authenticated-orcid":false,"given":"Luca","family":"Maggiulli","sequence":"first","affiliation":[{"name":"PSI Center for Energy and Environmental Sciences Paul Scherrer Institute  Villigen PSI CH\u20105232 Switzerland"},{"name":"Institute for Chemical and Bioengineering ETH Zurich  Vladimir\u2010Prelog\u2010Weg 1 Zurich 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