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Here, inspired by the natural calcification process of corals, we present a bio\u2010inspired capacitive decarbonization (CDC) reactor that sequesters dissolved inorganic carbon (DIC) from seawater as CaCO\n                    <jats:sub>3<\/jats:sub>\n                    using only seawater\u2010derived Ca\n                    <jats:sup>2+<\/jats:sup>\n                    and renewable electricity. The CDC system integrates a Ca\n                    <jats:sup>2+<\/jats:sup>\n                    \u2010selective electrode with a weak electric field to regulate ion transport and disrupt the hydration shell of Ca\n                    <jats:sup>2+<\/jats:sup>\n                    , enhancing its reaction with CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    . To address the limited concentration of CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    relative to Ca\n                    <jats:sup>2+<\/jats:sup>\n                    in seawater, we introduce an asymmetric electrosorption strategy to preferentially enrich CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    at the electrode interface, achieving a DIC conversion rate of up to 34% with an ultralow intrinsic electrochemical energy input of 2.5\u00a0kJ mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    CO\n                    <jats:sub>2<\/jats:sub>\n                    for the CDC reactor. The reactor exhibits stable continuous operation for over 100\u00a0h without fouling, enabled by spatially decoupled CaCO\n                    <jats:sub>3<\/jats:sub>\n                    precipitation. To mitigate the reduction in seawater alkalinity, we introduce a mineral\u2010assisted re\u2010alkalinization step that effectively restores pH and supports continued CO\n                    <jats:sub>2<\/jats:sub>\n                    absorption. A global integrated analysis model shows the CDC technology could remove up to 11\u2013438 million tonnes of CO\n                    <jats:sub>2<\/jats:sub>\n                    by 2050\u20132100. This work demonstrates a scalable and low\u2010energy solution for durable ocean carbon removal.\n                  <\/jats:p>","DOI":"10.1002\/anie.202515007","type":"journal-article","created":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T13:26:47Z","timestamp":1760016407000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Asymmetric Electrosorption in a Bio\u2010Inspired Reactor Enables Energy Efficient Ocean Carbon Removal"],"prefix":"10.1002","volume":"64","author":[{"given":"Yifang","family":"Zhu","sequence":"first","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences Ministry of Education Peking University  Beijing 100871 P.R. China"},{"name":"College of Environmental Sciences and Engineering Peking University  Beijing 100871 P.R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jay","family":"Fuhrman","sequence":"additional","affiliation":[{"name":"Joint Global Change Research Institute University of Maryland and Pacific Northwest National Laboratory College Park  Maryland MD USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haodong","family":"Ji","sequence":"additional","affiliation":[{"name":"Eco\u2010environment and Resource Efficiency Research Laboratory School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Lin","sequence":"additional","affiliation":[{"name":"SUSTech Energy Institute for Carbon Neutrality Department of Mechanical and Energy Engineering Southern University of Science and Technology  Shenzhen 518055 P.R. 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