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An in situ\u2010formed palladium(0)\u2013(\n                    <jats:italic>S<\/jats:italic>\n                    ,\n                    <jats:italic>S<\/jats:italic>\n                    )\u2010f\u2010Binaphane complex discriminates between the enantiotopic nonaflate groups, and the subsequent transmetalation of the B\u2013B reagent is enhanced by a copper co\u2010catalyst. The enantiomeric excess of the chiral monoborylated product after reductive elimination is further improved by a downstream kinetic resolution, thereby converting the minor enantiomer into the corresponding achiral bisborylated biaryl byproduct. This enantioselective Miyaura reaction enables the synthesis of highly valuable, axially chiral boron compounds with superb enantiomeric ratios (up to e.r.\u00a0= 99:1) and exhibits broad substrate scope and good functional\u2010group tolerance.\n                  <\/jats:p>","DOI":"10.1002\/anie.202515234","type":"journal-article","created":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:42:05Z","timestamp":1760406125000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Enantioselective Miyaura Reaction by Desymmetrizing C(sp\n                    <sup>2<\/sup>\n                    )\u2013B Cross\u2010Coupling of 1,1\u2032\u2010Biaryl\u20102,6\u2010diyl Bis(nonaflates)"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8980-1108","authenticated-orcid":false,"given":"Yao","family":"Xiao","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Technische Universit\u00e4t Berlin  Strasse des 17. 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