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We, herein, built a single\u2010molecule C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    trap that bears an opposite series of oxygen and dense alkyl groups distributed in an ultramicroporous [Al(OH)(trans\u2010CDC)] (Al\u2010CDC, trans\u2010H\n                    <jats:sub>2<\/jats:sub>\n                    CDC\u00a0=\u00a0trans\u20101,4\u2010cyclohexanedicarboxylic acid). The ultra\u2010stable trap with well\u2010matched pore size and pore chemistry enables a record uptake (40.8 cm\n                    <jats:sup>3<\/jats:sup>\n                    (STP) g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) at ultralow concentration, Henry coefficient (12685.5 cm\n                    <jats:sup>3<\/jats:sup>\n                    (STP) g\n                    <jats:sup>\u22121<\/jats:sup>\n                    bar\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), initial adsorption heat difference (27.2\u00a0kJ mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), adsorption kinetic (0.49 min\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and kinetic selectivity (3.1) for C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    with one of the highest initial C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    adsorption heats (50.5\u00a0kJ mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and selectivity (16.3), establishing a novel benchmark for capture of trace C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    . The C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    adsorption mechanism is deciphered to be thermodynamically driven owing to the synergism of multiple hydrogen\u2010bonding and van der Waals (vdW) forces. Breakthrough tests validate that Al\u2010CDC owns a record C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    productivity (\u226599.999%) of 410.5 cm\n                    <jats:sup>3<\/jats:sup>\n                    (STP) g\n                    <jats:sup>\u22121<\/jats:sup>\n                    for trace C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    capture with excellent reproducibility. The cost\u2010effective scalable production with the cheapest cost (508.9 $ kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and highest space\u2010time yield (4564.8\u00a0kg m\n                    <jats:sup>\u22123<\/jats:sup>\n                    day\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and shaping of Al\u2010CDC is realized with unaffected structural property and capture performance.\n                  <\/jats:p>","DOI":"10.1002\/anie.202515496","type":"journal-article","created":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T06:14:47Z","timestamp":1761286487000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Cost\u2010Effective Scalable Production of Ultra\u2010Stable Alkyl MOF Featuring Single\u2010Molecule C\n                    <sub>3<\/sub>\n                    H\n                    <sub>6<\/sub>\n                    Trap for Record Capture of Trace C\n                    <sub>3<\/sub>\n                    H\n                    <sub>6<\/sub>\n                    from C\n                    <sub>2<\/sub>\n                    H\n                    <sub>4<\/sub>"],"prefix":"10.1002","volume":"64","author":[{"given":"Miao","family":"Chang","sequence":"first","affiliation":[{"name":"School of Materials and Chemical Engineering Chuzhou University  Chuzhou 239000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zitong","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials and Chemical Engineering Chuzhou University  Chuzhou 239000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruihan","family":"Wang","sequence":"additional","affiliation":[{"name":"Chemical Engineering College Hebei Normal University of Science and Technology  Qinhuangdao 066600 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minghui","family":"Liu","sequence":"additional","affiliation":[{"name":"Petrochemical Research Institute, PetroChina  Beijing 102206 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3656-6773","authenticated-orcid":false,"given":"Yujie","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials and Chemical Engineering Chuzhou University  Chuzhou 239000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dahuan","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites Beijing University of Chemical Technology  Beijing 100029 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