{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T03:38:04Z","timestamp":1781149084140,"version":"3.54.1"},"reference-count":109,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2025,9,17]],"date-time":"2025-09-17T00:00:00Z","timestamp":1758067200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22201210"],"award-info":[{"award-number":["22201210"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22301122"],"award-info":[{"award-number":["22301122"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22101151"],"award-info":[{"award-number":["22101151"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2024A1515010842"],"award-info":[{"award-number":["2024A1515010842"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,11,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    We report the synthesis and cooperative reactivity of a bifunctional silylene\u2013aminoborane compound, 1\u2010Ph\u20102\u2010\n                    <jats:italic>\n                      <jats:sup>t<\/jats:sup>\n                    <\/jats:italic>\n                    Bu\u20101\n                    <jats:italic>H<\/jats:italic>\n                    \u20102,1\u2010benzazaborolyl\u2010(amidinato)silylene (\n                    <jats:bold>1<\/jats:bold>\n                    ), designed to preserve the ambiphilicity of both functional units while preventing intramolecular deactivation.\n                    <jats:bold>1<\/jats:bold>\n                    engages in unprecedented multicomponent activations of unsaturated bonds, including alkynes and phosphaalkynes, to construct novel main\u2010group element embedded polycyclic frameworks. Reaction with alkynes led to rare main\u2010group elements enriched semibullvalenes via highly regioselective [2\u00a0+\u00a02\u00a0+\u00a01] cycloaddition. Notably, reaction with a phosphaalkyne induced a distinct S\n                    <jats:sub>N<\/jats:sub>\n                    Ar\u2010like B\u2500C bond cleavage and formation of a B\u2500N\u2500Si\u2500P\u2010embedded barrelene analogue. Structural and computational analyses revealed the synergistic multi\u2010site activation modes and reaction pathways.\n                  <\/jats:p>","DOI":"10.1002\/anie.202515808","type":"journal-article","created":{"date-parts":[[2025,9,18]],"date-time":"2025-09-18T05:48:28Z","timestamp":1758174508000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Bifunctional Silylene\u2013Aminoborane Enables Cooperative Activation of Unsaturated Bonds and Access to Heteroatom\u2010Enriched Polycycle"],"prefix":"10.1002","volume":"64","author":[{"given":"Zheng","family":"Su","sequence":"first","affiliation":[{"name":"Tianjin Key Laboratory of Structure and Performance for Functional Molecules College of Chemistry Tianjin Normal University  Tianjin 300387 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingdong","family":"Zhong","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Structure and Performance for Functional Molecules College of Chemistry Tianjin Normal University  Tianjin 300387 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xixi","family":"Meng","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Structure and Performance for Functional Molecules College of Chemistry Tianjin Normal University  Tianjin 300387 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren","family":"Gao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiancheng","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Research Center for Chemical Biology and Omics Analysis College of Science Southern University of Science and Technology  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minyi","family":"Yuan","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Structure and Performance for Functional Molecules College of Chemistry Tianjin Normal University  Tianjin 300387 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Herbert W.","family":"Roesky","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Georg\u2010August\u2010Universit\u00e4t G\u00f6ttingen  G\u00f6ttingen 37077 Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0931-321X","authenticated-orcid":false,"given":"Shaoguang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,17]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00815J"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00101J"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214942"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/bs.adioch.2023.08.004"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198707761"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/a703054a"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1023\/B:SILC.0000025574.54359.7a"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/om050362l"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704939"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/om800854a"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9091374"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/hc.20705"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/om101066w"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201581"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/om300999e"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt31326j"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2DT32126B"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/om500947x"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03149"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/om960338v"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200105)627:5<1048::AID-ZAAC1048>3.0.CO;2-D"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01753a"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201001141"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01753a"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005866"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201104146"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja205369h"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201500271"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00368"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c01762"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12908"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c03140"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-023-00279-6"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202414696"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC06222H"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202401762"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114485"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja411951y"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600647"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402795"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505872"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5SC01812A"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202512084"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201700625"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203072"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3QI00079F"},{"key":"e_1_2_6_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT01955D"},{"key":"e_1_2_6_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT00523E"},{"key":"e_1_2_6_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202400786"},{"key":"e_1_2_6_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CC01930J"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410790"},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c10323"},{"key":"e_1_2_6_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c00949"},{"key":"e_1_2_6_55_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-38606-2"},{"key":"e_1_2_6_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507560"},{"key":"e_1_2_6_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5SC01104C"},{"key":"e_1_2_6_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.5c00028"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200063"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol070328y"},{"key":"e_1_2_6_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201505491"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.3c00355"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.orgel.2024.107154"},{"key":"e_1_2_6_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413370"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c03349"},{"key":"e_1_2_6_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja305581f"},{"key":"e_1_2_6_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT00812J"},{"key":"e_1_2_6_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800987"},{"key":"e_1_2_6_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202205358"},{"key":"e_1_2_6_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05136"},{"key":"e_1_2_6_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00305"},{"key":"e_1_2_6_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202215838"},{"key":"e_1_2_6_73_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04434"},{"key":"e_1_2_6_74_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC07109A"},{"key":"e_1_2_6_75_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202003611"},{"key":"e_1_2_6_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202219062"},{"key":"e_1_2_6_77_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504229"},{"key":"e_1_2_6_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja1031024"},{"key":"e_1_2_6_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja206702e"},{"key":"e_1_2_6_80_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja301042u"},{"key":"e_1_2_6_81_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c10467"},{"key":"e_1_2_6_82_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c00722"},{"key":"e_1_2_6_83_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415246"},{"key":"e_1_2_6_84_1","doi-asserted-by":"publisher","DOI":"10.1039\/B617136B"},{"key":"e_1_2_6_85_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198502291"},{"key":"e_1_2_6_86_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja000309i"},{"key":"e_1_2_6_87_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja057917o"},{"key":"e_1_2_6_88_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.07.005"},{"key":"e_1_2_6_89_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11913"},{"key":"e_1_2_6_90_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09040"},{"key":"e_1_2_6_91_1","unstructured":"Deposition Numbers 2464839 (compound1) 2464840 (compound2) 2464841 (compound3) 2464842 (compound4) and 2464843 (compound5) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service www.ccdc.cam.ac.uk\/structures."},{"key":"e_1_2_6_92_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4DT01367K"},{"key":"e_1_2_6_93_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201103192"},{"key":"e_1_2_6_94_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c02535"},{"key":"e_1_2_6_95_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed058p32"},{"key":"e_1_2_6_96_1","volume-title":"Program for Area Detector Absorption Correction","author":"Sheldrick G. M.","year":"1996"},{"key":"e_1_2_6_97_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_6_98_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_6_99_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889808042726"},{"key":"e_1_2_6_100_1","unstructured":"M. J.Frisch G. W.Trucks H. B.Schlegel G. E.Scuseria M. A.Robb J. R.Cheeseman G.Scalmani V.Barone G. A.Petersson H.Nakatsuji X.Li M.Caricato A. V.Marenich J.Bloino B. G.Janesko R.Gomperts B.Mennucci H. P.Hratchian J. V.Ortiz A. F.Izmaylov J. L.Sonnenberg D.Williams\u2010Young F.Ding F.Lipparini F.Egidi J.Goings B.Peng A.Petrone T.Henderson D.Ranasinghe et\u00a0al Gaussian Inc. Wallingford CT 2016."},{"key":"e_1_2_6_101_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"e_1_2_6_102_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"},{"key":"e_1_2_6_103_1","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"e_1_2_6_104_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-007-0310-x"},{"key":"e_1_2_6_105_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp810292n"},{"key":"e_1_2_6_106_1","unstructured":"NBO 7.0.E. D.Glendening J. K.Badenhoop A. E.Reed J. E.Carpenter J. A.Bohmann C. M.Morales P.Karafiloglou C. R.Landis F.Weinhold Theoretical Chemistry Institute University of Wisconsin Madison WI2018."},{"key":"e_1_2_6_107_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_2_6_108_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0216272"},{"key":"e_1_2_6_109_1","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202515808","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,12]],"date-time":"2025-11-12T07:47:03Z","timestamp":1762933623000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202515808"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,17]]},"references-count":109,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2025,11,3]]}},"alternative-id":["10.1002\/anie.202515808"],"URL":"https:\/\/doi.org\/10.1002\/anie.202515808","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,17]]},"assertion":[{"value":"2025-07-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-12","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202515808"}}