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However, synthesizing atomically layered platinum intermetallic catalysts remains challenging due to platinum\u2019s bulk crystallization tendency. Herein, we first prepare Pt\n                    <jats:sub>5<\/jats:sub>\n                    GaP and Pt\n                    <jats:sub>5<\/jats:sub>\n                    InP nanoparticles with self\u2010supported interlayer tunnels via pillar nanoengineering, featuring Pt\n                    <jats:sub>5<\/jats:sub>\n                    X (X = Ga\/In) tri\u2010layers alternating with \u201cP pillars\u201d. The pillar effect enables selective H\n                    <jats:sub>2<\/jats:sub>\n                    transport while blocking CO, endowing superior full\u2010pH HOR activity and CO tolerance vs. commercial Pt\/C. Pt\n                    <jats:sub>5<\/jats:sub>\n                    InP exhibits 13.9\u2010 and 11.5\u2010fold higher mass activity than Pt\/C at pH = 1 and 13 (50 mV overpotential) with exceptional CO resistance. This novel layered compound and generalizable strategy pave the way for atomic\u2010scale platinum\u2010based catalysts, offering a tunnel size\u2010dependent CO\u2010tolerant approach and expanding small\u2010molecule catalysis applicability.\n                  <\/jats:p>","DOI":"10.1002\/anie.202515811","type":"journal-article","created":{"date-parts":[[2025,12,19]],"date-time":"2025-12-19T09:45:57Z","timestamp":1766137557000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Atomic\u2010Layered Platinum\u2010Based Intermetallic with Phosphorus Pillar Nanoengineering Enables pH\u2010Universal Hydrogen Oxidation Catalysis"],"prefix":"10.1002","volume":"65","author":[{"given":"Renjie","family":"Gui","sequence":"first","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 P.R. 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