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However, many of these supramolecular scaffolds face challenges in incorporating bulky or hydrophilic ligands, such as carbohydrates. This issue often requires the co\u2010assembly of ligand\u2010containing blocks with non\u2010functionalized ones, diluting ligand presentation and compromising their precise spatial arrangement. Herein, we present carbohydrate oligomers that assemble into supramolecular nanomaterials featuring a molecularly controlled, dense presentation of carbohydrate ligands on their surfaces. This modular system accommodates a variety of carbohydrate ligands while maintaining consistent bulk material properties. 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