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However, the strong intermolecular hydrogen bonds within the cellulose framework hinder lithium ion (Li\n                    <jats:sup>+<\/jats:sup>\n                    ) transport and reduce ion mobility, limiting their practical applications. In this study, we developed a cellulose trimellitate ester (PCLA) with a double\u2010donor and anion\u2010\u03c0 structure: 1) the carbonyl group (C\u2550O) as a Li\n                    <jats:sup>+<\/jats:sup>\n                    donor, 2) the carboxyl group (COOH) serves as a hydrogen bond donor to anchor the bis(trifluoromethanesulfonyl)imide (TFSI\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) anion, and 3) the electron\u2010deficient benzene ring (Ph) interacts with the TFSI\n                    <jats:sup>\u2212<\/jats:sup>\n                    anion through the anion\u2010\u03c0 mechanism. The resulting PCLA QPE achieved high ionic conductivity (1\u00a0\u00d7\u00a010\n                    <jats:sup>\u22123<\/jats:sup>\n                    S cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 25 \u00b0C) and excellent tensile strength (57.04\u00a0MPa). Full\u2010cell batteries with LFP and NCM811 cathodes exhibited exceptional cycling stability with remaining 85% and 90% of their initial capacity after 1000 and 200 cycles, respectively. This double\u2010donor and anion\u2010\u03c0 molecular design paves the way for cellulose\u2010based solid electrolytes with commercial potential, advancing next\u2010generation safe energy storage technologies.\n                  <\/jats:p>","DOI":"10.1002\/anie.202516098","type":"journal-article","created":{"date-parts":[[2025,10,23]],"date-time":"2025-10-23T12:20:47Z","timestamp":1761222047000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Double\u2010Donor and Anion\u2010\u03c0 Polymer Electrolytes for Fast Li\n                    <sup>+<\/sup>\n                    Conduction in Lithium Metal Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Yucheng","family":"Liu","sequence":"first","affiliation":[{"name":"National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced Microstructures Jiangsu Key Laboratory of Artificial Functional Materials College of Engineering and Applied Sciences Nanjing University  Nanjing 210093 P.R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaohui","family":"Cheng","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced Microstructures Jiangsu Key Laboratory of Artificial Functional Materials College of Engineering and Applied Sciences Nanjing University  Nanjing 210093 P.R. China"},{"name":"School of Materials Science and Engineering Hunan University of Technology  Zhuzhou 412007 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2573-9584","authenticated-orcid":false,"given":"Yu","family":"Ding","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced Microstructures Jiangsu Key Laboratory of Artificial Functional Materials College of Engineering and Applied Sciences Nanjing University  Nanjing 210093 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4400-708X","authenticated-orcid":false,"given":"Shaochun","family":"Tang","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced Microstructures Jiangsu Key Laboratory of Artificial Functional Materials College of Engineering and Applied Sciences Nanjing University  Nanjing 210093 P.R. 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