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However, acidic CO\n                    <jats:sub>2<\/jats:sub>\n                    RR has been hindered by the severe competing hydrogen evolution reaction (HER) and sluggish carbon\u2013carbon coupling efficiency. Herein, an ion\u2010transport regulation strategy has been developed to customize the microenvironment near cathode surface during high current density electrolysis in acidic electrolyte. A hybrid adlayer composed of (010) planes\u2010enclosed ZrO\n                    <jats:sub>2<\/jats:sub>\n                    nanosheets and Nafion preferentially allows K\n                    <jats:sup>+<\/jats:sup>\n                    transport toward cathode through proton trapping and Donnan effect, thus simultaneously enriching K\n                    <jats:sup>+<\/jats:sup>\n                    and raising pH near cathode surface during CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. Such K\n                    <jats:sup>+<\/jats:sup>\n                    \u2010rich and alkaline microenvironment suppresses HER and favors C\n                    <jats:sub>2+<\/jats:sub>\n                    products formation. Particularly, a remarkable C\n                    <jats:sub>2+<\/jats:sub>\n                    Faraday efficiency (FE) of nearly 81% has been achieved with a partial current density of 484\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for C\n                    <jats:sub>2+<\/jats:sub>\n                    products on modified Cu electrode. This work demonstrates an effective strategy to boost the CO\n                    <jats:sub>2<\/jats:sub>\n                    RR performance in acidic electrolyzers for efficient and sustainable CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion.\n                  <\/jats:p>","DOI":"10.1002\/anie.202516139","type":"journal-article","created":{"date-parts":[[2025,11,6]],"date-time":"2025-11-06T12:48:32Z","timestamp":1762433312000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Selective Ion Transport Regulation Enables High Current Density CO\n                    <sub>2<\/sub>\n                    \u2010to\u2010C\n                    <sub>2+<\/sub>\n                    Conversion in Acid"],"prefix":"10.1002","volume":"65","author":[{"given":"Yue","family":"Yang","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Silicon and Advanced Semiconductor Materials Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanyang","family":"Qin","sequence":"additional","affiliation":[{"name":"School of Chemistry Xi'an Key Laboratory of Sustainable Energy Materials Chemistry State Key Laboratory of Electrical Insulation and Power Equipment Engineering Research Center of Energy Storage Materials and Devices of Ministry of Education Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunhao","family":"Zhong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Clean Energy Utilization Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangzhou","family":"Lv","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Silicon and Advanced Semiconductor Materials Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengjie","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Silicon and Advanced Semiconductor Materials Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Liu","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Shenzhen Polytechnic University  7098 Liuxian Boulevard Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Angjian","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Clean Energy Utilization Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaqiong","family":"Su","sequence":"additional","affiliation":[{"name":"School of Chemistry Xi'an Key Laboratory of Sustainable 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