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Here, we develop a one\u2010pot cycloaddition\u2013transesterification\u2013glycolysis (CTG) tandem process to efficiently convert PET, CO\n                    <jats:sub>2<\/jats:sub>\n                    , and glycerol into bis\u2010hydroxyethyl terephthalate (BHET) and glycerol carbonate, achieving yields of 92% and 99%, respectively. The process begins with the cycloaddition of ethylene oxide and CO\n                    <jats:sub>2<\/jats:sub>\n                    in an ionic liquid, followed by transesterification with glycerol to produce glycerol carbonate and ethylene glycol. The in situ\u2010generated ethylene glycol participates in PET glycolysis to yield BHET catalyzed by zinc acetate. Kinetic studies, isotope labelling, and theoretical calculations reveal that ethylene oxide serves two functions: (i) swelling the PET matrix to enhance mass transfer and (ii) providing ethylene glycol. The synchronized kinetics of cycloaddition, transesterification, and glycolysis enable ethylene oxide to play both roles effectively, significantly accelerating PET depolymerization at mild temperatures.\n                  <\/jats:p>","DOI":"10.1002\/anie.202516172","type":"journal-article","created":{"date-parts":[[2025,11,3]],"date-time":"2025-11-03T08:48:17Z","timestamp":1762159697000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Integrated Conversion of Polyesters, CO\n                    <sub>2<\/sub>\n                    , and Glycerol via Ethylene Oxide\u2010Mediated Tandem Process"],"prefix":"10.1002","volume":"64","author":[{"given":"Cong","family":"Luo","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyu","family":"Cen","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weilong","family":"Wen","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianrui","family":"Bi","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiye","family":"Ma","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Ma","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junfeng","family":"Xiang","sequence":"additional","affiliation":[{"name":"Center for Physicochemical Analysis Measurement Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 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University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Longfei","family":"Lin","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0440-809X","authenticated-orcid":false,"given":"Buxing","family":"Han","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for 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