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To overcome this, a multi\u2010functional system is required by two or more functional units combined in one catalyst, with each unit playing a complementary role. Here we find that the Au site of Au(TBBT)PPh\n                    <jats:sub>3<\/jats:sub>\n                    (TBBT\u00a0=\u00a04\u2010\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butylbenzenethiol) complex not only activates water but also reduces nitrate to ammonia, resulting in a low efficiency for the electrocatalytic reduction of nitrate. To decouple the responsibility of the Au site, we synthesize a Ru\n                    <jats:sub>1<\/jats:sub>\n                    Au\n                    <jats:sub>6<\/jats:sub>\n                    (TBBT)\n                    <jats:sub>6<\/jats:sub>\n                    (PPh\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>6<\/jats:sub>\n                    cluster consisted of one Ru atom and six Au(TBBT)PPh\n                    <jats:sub>3<\/jats:sub>\n                    complexes bridged by the S atoms, in which the water dissociation is mostly undertaken on the Ru site for the steady supply of proton, while the nitrate is sequentially reduced on the Au sites. More notably, the hopping of proton from Ru to Au is readily proceeded over the S bridge, giving rise to positively cooperative couple of one Ru site and six Au sites among this cluster, and thereby 19\u2010fold efficiency increase is observed in comparison to this complex catalyst.\n                  <\/jats:p>","DOI":"10.1002\/anie.202516398","type":"journal-article","created":{"date-parts":[[2025,10,18]],"date-time":"2025-10-18T16:12:21Z","timestamp":1760803941000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["An Atomically Precise Ru\n                    <sub>1<\/sub>\n                    Au\n                    <sub>6<\/sub>\n                    (TBBT)\n                    <sub>6<\/sub>\n                    (PPh\n                    <sub>3<\/sub>\n                    )\n                    <sub>6<\/sub>\n                    Cluster Catalyst for Ammonia Production"],"prefix":"10.1002","volume":"64","author":[{"given":"Jinzhi","family":"Lu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Key Laboratory of Mesoscopic Chemistry of Ministry of Education School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenyang","family":"Shen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Key Laboratory of Mesoscopic Chemistry of Ministry of Education School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiqi","family":"Tian","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Key Laboratory of Mesoscopic Chemistry of Ministry of Education School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 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2475063 for Ru1Au6(TBBT)6(PPh3)6and CCDC 2475064 for Au(TBBT)PPh3contain the crystallographic data for this paper and can be obtained free of charge from The Cambridge Crystallographic Data Centra 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