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The compound was accessed by means of a double bond metathesis reaction between an amido\u2010functionalized phosphinidene oxide, BnArNP\u2550O (Ar\u00a0=\u00a0bulky aryl substituent), with a silylene telluride, L(NMe\n                    <jats:sub>2<\/jats:sub>\n                    )Si\u2550Te (L\u00a0=\u00a0PhC(N\n                    <jats:italic>\n                      <jats:sup>t<\/jats:sup>\n                    <\/jats:italic>\n                    Bu)\n                    <jats:sub>2<\/jats:sub>\n                    ). The resulting phosphinidene telluride, BnArNP\u2550Te, exhibits a short P\u2550Te bond (2.297(1) \u00c5), resulting from a significant p\n                    <jats:sub>\u03c0<\/jats:sub>\n                    \u2013p\n                    <jats:sub>\u03c0<\/jats:sub>\n                    orbital interaction between the phosphorus(III) and tellurium(\u2212II) atoms. Key to the stabilization of this compound is the amido substituent associated with the phosphorus atom, which provides kinetic stabilization due to its steric bulk but also significant thermodynamic stabilization through negative hyperconjugation of the nitrogen atom lone pair into antibonding orbital interactions between phosphorus and tellurium. The title compound acts as a versatile phosphinidene transfer platform, accompanied by the extrusion of elemental tellurium to afford other phosphorus(III) compounds via transient phosphorus(V) intermediates.\n                  <\/jats:p>","DOI":"10.1002\/anie.202516494","type":"journal-article","created":{"date-parts":[[2025,9,12]],"date-time":"2025-09-12T11:37:49Z","timestamp":1757677069000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis, Isolation, and Reactivity of a Phosphinidene Telluride"],"prefix":"10.1002","volume":"64","author":[{"given":"Chenyang","family":"Hu","sequence":"first","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 USA"},{"name":"Department of Chemistry Chemistry Research Laboratory University of Oxford  12 Mansfield Rd. Oxford OX1 3TA UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"\u00c1lvaro","family":"Garc\u00eda\u2010Romero","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Debanik","family":"Ray","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maren","family":"Pink","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7311-1663","authenticated-orcid":false,"given":"Jose M.","family":"Goicoechea","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,9,12]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)87450-1"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)88840-3"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1979-0223"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.34a-0333"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.38a-0349"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1990-0717"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/DT9950001887"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic020562e"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2004.04.028"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200501138"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic701611p"},{"key":"e_1_2_8_12_1","first-page":"187","volume":"35","author":"Beckman J.","year":"2012","journal-title":"Main Group Met. 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