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Herein, we report the phase engineering of Mg\u2013Pt intermetallic catalysts achieved through the precise control of reactive metal\u2013support interactions (RMSIs) between Pt nanoparticles (NPs) and Mg supports. By manipulating Pt crystallinity, we synthesized two distinct phases, Mg\n                    <jats:sub>29<\/jats:sub>\n                    Pt\n                    <jats:sub>4<\/jats:sub>\n                    and Mg\n                    <jats:sub>3<\/jats:sub>\n                    Pt. In the presence of CO, Mg\n                    <jats:sub>29<\/jats:sub>\n                    Pt\n                    <jats:sub>4<\/jats:sub>\n                    demonstrates remarkable activity for selective hydrogenation reactions, contrasting sharply with the almost complete deactivation of metallic Pt. Notably, Mg\n                    <jats:sub>29<\/jats:sub>\n                    Pt\n                    <jats:sub>4<\/jats:sub>\n                    retains \u223c88% of its original activity when exposed to 0.2 vol% CO, a typical industrial crude hydrogen concentration, outperforming state\u2010of\u2010the\u2010art\u00a0Pt catalysts. This superior CO tolerance arises from its electron\u2010rich Pt sites and low d\u2010band center, which suppress electron donation from CO 5\u03c3 orbitals to Pt 5d orbitals while hindering electron back\u2010donation from Pt d orbitals to CO 2\u03c0* antibonding orbitals. Moreover, Mg\n                    <jats:sub>29<\/jats:sub>\n                    Pt\n                    <jats:sub>4<\/jats:sub>\n                    also facilitates the hydrogenation of diverse functional groups, including alkynes, aldehydes, and nitroarenes, while maintaining excellent CO tolerance. This work demonstrates that manipulating the electronic properties of Pt single\u2010atom sites can alter CO adsorption behavior, enabling the design of efficient Pt catalysts for anti\u2010CO poisoning.\n                  <\/jats:p>","DOI":"10.1002\/anie.202516790","type":"journal-article","created":{"date-parts":[[2025,11,3]],"date-time":"2025-11-03T07:27:52Z","timestamp":1762154872000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Phase Engineering of Mg\u2013Pt Intermetallic Hydrogenation Catalysts for CO Poisoning Resistance"],"prefix":"10.1002","volume":"65","author":[{"given":"Xiaojun","family":"Lu","sequence":"first","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Polyolefins and Catalysis School of Chemistry and Chemical Engineering Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai 200240 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of Space Power\u2010Sources  Shanghai 200245 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangfan","family":"Lu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering National Engineering Research Center for Mg Alloys National Key Laboratory of Advanced Casting Technologies National Innovation Center for Industry\u2010Education Integration of Energy Storage Technology Chongqing University  Chongqing 400045 China"},{"name":"Chongqing Institute of New Energy Storage Materials and Equipment  Chongqing 401135 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sijia","family":"Zheng","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Polyolefins and Catalysis School of Chemistry and Chemical Engineering Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai 200240 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School of Chemistry and Chemical Engineering Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kailong","family":"Qian","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Polyolefins and Catalysis School of Chemistry and Chemical Engineering Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Du","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201204 China"},{"name":"Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai 201204 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