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Here, we present an example of a heterodimetallic monomeric complex [(Trapen\n                    <jats:sup>CH2PPh2<\/jats:sup>\n                    )U(Co)] (\n                    <jats:bold>4<\/jats:bold>\n                    ) containing a U\u2013Co triple bond, which was synthesized by the reaction of [(Trapen\n                    <jats:sup>CH2PPh2<\/jats:sup>\n                    )U(Cl)] (\n                    <jats:bold>2<\/jats:bold>\n                    ) or [(Trapen\n                    <jats:sup>CH2PPh2<\/jats:sup>\n                    )U] (\n                    <jats:bold>3<\/jats:bold>\n                    ) with CoCl\n                    <jats:sub>2<\/jats:sub>\n                    in the presence of KC\n                    <jats:sub>8<\/jats:sub>\n                    . The crystal structure of\n                    <jats:bold>4<\/jats:bold>\n                    reveals a highly\u00a0symmetrical\u00a0geometry with a linear Co\u2013U\u2013N\n                    <jats:sub>amine<\/jats:sub>\n                    axis line, and the U\u2013Co bond length 2.1890(11) \u00c5 is slightly longer than the sum of the covalent triple\u2010bond radii of uranium and cobalt (2.14\u00a0\u00c5). The U\u2013N\n                    <jats:sub>amine<\/jats:sub>\n                    bond length (2.439(6) \u00c5) is significantly shortened compared to that of precursors\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    . The significant contraction of the U\u2013N\n                    <jats:sub>amine<\/jats:sub>\n                    bond demonstrates electronic reinforcement via the inverse trans\u2010influence (ITI). Detailed computational investigations further support the existence of a U\u2261Co triple bond in\n                    <jats:bold>4<\/jats:bold>\n                    , and the formal oxidation states of uranium and cobalt appear to be U(IV) and Co(\u2010I). The low\u2010temperature magnetic moments of\n                    <jats:bold>4<\/jats:bold>\n                    are approaching 2.1 \u03bc\n                    <jats:sub>B<\/jats:sub>\n                    , which is attributed to its near\u2010doubly degenerate spin\u2010orbit ground states in the pseudo\u2010C\n                    <jats:sub>3v<\/jats:sub>\n                    symmetry. Remarkably,\n                    <jats:bold>4<\/jats:bold>\n                    served as the catalyst for the hydroboration and dimerization of terminal alkynes under mild conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202516858","type":"journal-article","created":{"date-parts":[[2025,9,15]],"date-time":"2025-09-15T05:48:31Z","timestamp":1757915311000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["A Heterodimetallic Monomeric Complex with a Uranium\u2013Cobalt Triple Bond"],"prefix":"10.1002","volume":"64","author":[{"given":"Kang","family":"Liu","sequence":"first","affiliation":[{"name":"Laboratory of Nuclear Energy Chemistry Institute of High Energy Physics Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Guo","sequence":"additional","affiliation":[{"name":"Laboratory of Nuclear Energy Chemistry Institute of High 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Chemistry of Ministry of Education School of Chemistry IGCME GBRCE for Functional Molecular Engineering Sun Yat\u2010Sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jipan","family":"Yu","sequence":"additional","affiliation":[{"name":"Laboratory of Nuclear Energy Chemistry Institute of High Energy Physics Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Guangdong Provincial Key Laboratory of Catalytic Chemistry Southern University of Science and Technology  Shenzhen 518055 China"},{"name":"Department of Chemistry and Engineering Research Center of Advanced Rare\u2010Earth Materials of Ministry of Education Tsinghua University  Beijing 100084 China"},{"name":"Fundamental Science Center of Rare Earths Ganjiang Innovation Academy Chinese Academy of Sciences  Ganzhou 341000 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