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However, the insufficient supply of *CO\/CO severely limits the rate of C\u2013C coupling toward C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    . Herein, we present a synergistic engineering strategy to construct a Fe\n                    <jats:sub>0.2<\/jats:sub>\n                    \/H\u2010MOF\u20101 composite catalyst by anchoring high\u2010density iron single atoms sites (Fe SAs) onto a pyridinic nitrogen rich metal\u2013organic framework (H\u2010MOF\u20101). Under visible light, the catalyst achieves an exceptional C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    yield of 1056.2 \u00b5mol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This performance surpasses state\u2010of\u2010the\u2010art systems for visible light driven CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    . The X\u2010ray absorption fine structure (XAFS) analysis, CO adsorption experiments and density functional theory (DFT) calculations demonstrate that the Fe\u2010N active sites in the Fe\n                    <jats:sub>0.2<\/jats:sub>\n                    \/H\u2010MOF\u20101 catalyst not only significantly reduce the energy barrier from *COOH to *CO but also maintain abundant *CO\/CO for C\u2013C coupling through strong CO adsorption, thus efficiently promoting the rapid generation of C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    . This study provides insights into the rapid generation of C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    through photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction, paving the way for visible light\u2010driven CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202517013","type":"journal-article","created":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T10:56:53Z","timestamp":1760698613000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Optimizing *CO\/CO Supply by Atomically Dispersed Fe Sites for High\u2010rate CO\n                    <sub>2<\/sub>\n                    \u2010to\u2010C\n                    <sub>2<\/sub>\n                    H\n                    <sub>4<\/sub>\n                    Conversion Under Visible Light"],"prefix":"10.1002","volume":"64","author":[{"given":"Ting","family":"Zhou","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Environmental and Chemical Engineering Jiangsu University of Science and Technology  Zhenjiang 212003 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tixuan","family":"Xia","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Menglu","family":"Wei","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang 212013 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