{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:14:46Z","timestamp":1791728086737,"version":"4.3.4"},"reference-count":38,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2025,9,11]],"date-time":"2025-09-11T00:00:00Z","timestamp":1757548800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFE0211200"],"award-info":[{"award-number":["2024YFE0211200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22002119"],"award-info":[{"award-number":["22002119"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,11,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrochemical carbon dioxide reduction (CO\n                    <jats:sub>2<\/jats:sub>\n                    R) to generate value added methanol (MeOH) in water has been considered as a potential strategy to realize efficient carbon cycle and reutilization. Cobalt phthalocyanine (CoPc) represents as a classical molecular catalyst carrying precisely tunable active sites, which has been widely explored for the CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010MeOH conversion, but optimization of performance is suffering from relatively easiness in desorption of *CO intermediate. To this end, we developed a novel molecular assembly of CoPc nanotubes (CoT) driven by van der Waals force with surface being modified by poly(4\u2010vinylpyridine). The as\u2010derived catalyst exhibited an exceptional performance of MeOH production for the turnover frequency enhanced by more than 14\u2010fold compared to the pristine CoT, and the Faradaic efficiency is up to 40% at a moderate potential. It revealed that the pyridyl groups of P4VP axially coordinated with the Co catalytic centers shifted the d\u2010band center toward the Fermi level, which strengthened the chemisorption and activation of *CO intermediates, thereby decreasing the whole barrier to produce MeOH. This work demonstrates a novel insight into intermediate manipulation of CO\n                    <jats:sub>2<\/jats:sub>\n                    R and highlights the potential of molecular electrocatalysis for carbon valorization.\n                  <\/jats:p>","DOI":"10.1002\/anie.202517033","type":"journal-article","created":{"date-parts":[[2025,9,11]],"date-time":"2025-09-11T12:01:39Z","timestamp":1757592099000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Strengthening Intermediate Adsorption on a Cobalt Phthalocyanine Assembly by Polymeric Modification for Electrochemical Carbon Dioxide Reduction into Methanol"],"prefix":"10.1002","volume":"64","author":[{"given":"Poe Ei Phyu","family":"Win","sequence":"first","affiliation":[{"name":"Innovation Center for Chemical Science Jiangsu Key Laboratory of Advanced Negative Carbon Technologies College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Xu","sequence":"additional","affiliation":[{"name":"Innovation Center for Chemical Science Jiangsu Key Laboratory of Advanced Negative Carbon Technologies College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lilong","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education State\u2010Local Joint Laboratory for Comprehensive Utilization of Biomass Center for R&amp;D of Fine Chemicals Guizhou University  Guiyang 550025 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Yang","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education State\u2010Local Joint Laboratory for Comprehensive Utilization of Biomass Center for R&amp;D of Fine Chemicals Guizhou University  Guiyang 550025 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shibin","family":"Ren","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Pharmaceutical and Chemical Engineering Taizhou University  Taizhou 318000 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Shaanxi Normal University  Xi'an 710062 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2691-5105","authenticated-orcid":false,"given":"Jiong","family":"Wang","sequence":"additional","affiliation":[{"name":"Innovation Center for Chemical Science Jiangsu Key Laboratory of Advanced Negative Carbon Technologies College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. 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