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Here, we report a reversible light\u2010handedness\u2010dependent switching mechanism between photocatalysis and photothermal catalysis using a standard Au@CdS nanocatalyst functionalized with chiral cysteine ligands. The switching behavior is governed by the interplay of chemical chirality and circularly polarized light, mediated by the chirality\u2010induced spin selectivity effect. When the handedness of circularly polarized light matches the catalyst's chirality, spin\u2010polarized carriers are efficiently transferred, favoring photocatalysis. In contrast, mismatched conditions suppress charge transfer, enhance recombination, and induce localized heating, shifting the reaction toward photothermal catalysis. Tuning the handedness of circularly polarized light to mismatch the catalyst chirality induces a significant photothermal effect, with temperatures reaching 343 K and hydrogen evolution rates of up to 4.8 mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , doubling the performance in the matched case. This study introduces a light\u2010handedness\u2010controlled catalytic switch that enables dynamic modulation between two reaction modes using the same chiral catalyst, advancing our mechanistic understanding of spin\u2010dependent photothermal phenomena and establishing a versatile platform for optically tunable solar fuel production. The interaction of chemical and optical chirality offers a novel approach to designing next\u2010generation photocatalysts that can be tailored for energy conversion.\n                  <\/jats:p>","DOI":"10.1002\/anie.202517047","type":"journal-article","created":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T06:24:47Z","timestamp":1761287087000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Optical Switching of Catalytic Pathways for Hydrogen Generation via Light\u2010Handedness Control on Chiral Nanostructures"],"prefix":"10.1002","volume":"64","author":[{"given":"Qingli","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Beijing Institute of Technology  No. 5 South Zhongguancun Street, Haidian District Beijing 100081 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