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We report a truly multifunctional material based on a coordination framework employing photoluminescent uranyl(VI) cations bonded through cyanido bridges to cobalt(III) centers and between themselves by hydroxido and 1,4\u2010diazabicyclo[2.2.2]octane\u2010\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2019\u2010dioxide linkers. This material reveals proton conduction, dielectric relaxation, and visible light emission, all switchable by relative humidity (\n                    <jats:italic>RH<\/jats:italic>\n                    ). Moreover, the reported system shows affinity to organic solvents, which efficiently quench the emission. The sorption with a\n                    <jats:italic>RH<\/jats:italic>\n                    \u2010reversible shape\u2010memory effect was found for methanol and acetonitrile vapors, while the unusual\n                    <jats:italic>RH<\/jats:italic>\n                    \u2010activated sorption appears for ethanol. More importantly, the adsorption of simple alcohols activates visible\u2010light photochromism, leading to an optical memory effect present after their desorption. The observed adsorption of solvents and the related modification of the optical properties are possible not only due to the flexibility of the framework but also owing to extraordinarily labile coordination sites of uranium(VI) centers involving aqua and bridging hydroxido ligands, which can be selectively exchanged by specific solvent molecules.\n                  <\/jats:p>","DOI":"10.1002\/anie.202517109","type":"journal-article","created":{"date-parts":[[2025,9,30]],"date-time":"2025-09-30T08:18:53Z","timestamp":1759220333000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Proton Conduction, Dielectric Relaxation, Photoluminescence, and Photochromism Governed by Humidity and Alcohol Vapors in a Uranyl\u2013Cobalt Framework with Labile Coordination Sites"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9511-5270","authenticated-orcid":false,"given":"Jakub 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