{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T19:07:43Z","timestamp":1792177663045,"version":"4.4.0"},"reference-count":43,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2025,9,8]],"date-time":"2025-09-08T00:00:00Z","timestamp":1757289600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22302002"],"award-info":[{"award-number":["22302002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22375006"],"award-info":[{"award-number":["22375006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,11,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Urea photosynthesis from CO\n                    <jats:sub>2<\/jats:sub>\n                    and N\n                    <jats:sub>2<\/jats:sub>\n                    has profound environmental and energy implications. However, the simultaneous activation of CO\n                    <jats:sub>2<\/jats:sub>\n                    and N\n                    <jats:sub>2<\/jats:sub>\n                    , along with the promotion of C\u2500N bond formation, remains a major challenge. Herein, the asymmetric interfacial sites (Zn\u2500O\u2500Ti) were engineered by building oxygen atom bridges between ZIF\u20108 and MIL\u2010125 to enable efficient photocatalytic urea synthesis. The optimized Zn\u2500O\u2500Ti interface structure achieves a urea yield of 130\u00a0\u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in pure water and an apparent quantum yield of 5.52% at 350\u00a0nm, outperforming most materials reported for urea photosynthesis. Mechanistic studies reveal that Zn sites catalyze the conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    to *CO species, while Ti sites adsorb and activate N\n                    <jats:sub>2<\/jats:sub>\n                    to generate *NH\u2013NH species. The asymmetric interfacial sites lower the energy barrier for the coupling of *CO and *NH\u2013NH to form *CONH\n                    <jats:sub>2<\/jats:sub>\n                    intermediates, thereby promoting urea photosynthesis. This work provides significant insights into designing interfacial asymmetric sites to facilitate photosynthetic organic chemicals for upgrading the nitrogen cycle.\n                  <\/jats:p>","DOI":"10.1002\/anie.202517121","type":"journal-article","created":{"date-parts":[[2025,9,9]],"date-time":"2025-09-09T05:45:43Z","timestamp":1757396743000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Interfacial Zn\u2500O\u2500Ti Sites for Efficient Photocatalytic Urea Synthesis from CO\n                    <sub>2<\/sub>\n                    and N\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0223-7119","authenticated-orcid":false,"given":"Jiaojiao","family":"Fang","sequence":"first","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science Anhui Normal University  Wuhu 241002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Wu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science Anhui Normal University  Wuhu 241002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiling","family":"Hu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science Anhui Normal University  Wuhu 241002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hangmin","family":"Xu","sequence":"additional","affiliation":[{"name":"College of Environmental Science and Engineering, Institute of Technology for Carbon Neutralization Yangzhou University  Yangzhou 225009 P.R China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anni","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science Anhui Normal University  Wuhu 241002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yukai","family":"Chen","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering Changzhou University  Changzhou 213164 P.R China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingwang","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Environmental Science and Engineering, Institute of Technology for Carbon Neutralization Yangzhou University  Yangzhou 225009 P.R China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junjie","family":"Mao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science Anhui Normal University  Wuhu 241002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-024-01302-0"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33258-0"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10784"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202318589"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c10233"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01020-4"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409019"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2021.11.009"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-0481-9"},{"key":"e_1_2_7_10_1","author":"Ding B.","year":"2025","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303806"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-46745-3"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409163"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316973"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36778-5"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202507144"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207793"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202406515"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123056"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202110158"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314408"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202401333"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33066-6"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123146"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216835"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312076"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202400201"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-021-00741-3"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00368F"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207793"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202405637"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC00417K"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409799"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108892"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.163191"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.137958"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404258"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14586"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05633"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c05660"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-025-01914-3"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c01956"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402215"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202517121","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,12]],"date-time":"2025-11-12T07:46:06Z","timestamp":1762933566000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202517121"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,8]]},"references-count":43,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2025,11,3]]}},"alternative-id":["10.1002\/anie.202517121"],"URL":"https:\/\/doi.org\/10.1002\/anie.202517121","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,8]]},"assertion":[{"value":"2025-08-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-02","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202517121"}}