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In this study, we propose a \u201cB\u2190N coordination\u2010directed self\u2010locking\u201d strategy to construct robust single\u2010crystalline ONTs (named as\n                    <jats:bold>CityU\u201056<\/jats:bold>\n                    ). Single crystals of\n                    <jats:bold>CityU\u201056<\/jats:bold>\n                    are assembled via the formation of dynamic B\u2190N bonds between 2,2\u2032,7,7\u2032\u2010tetra(4\u2010pyridyl)\u20109,9\u2032\u2010spirobifluorene (SPFPY) and 1,4\u2010bis(benzodioxaborole)benzene (BACT). Single\u2010crystal X\u2010ray diffraction analysis indicates that\n                    <jats:bold>CityU\u201056<\/jats:bold>\n                    possesses a well\u2010defined prismatic nanotube structure with highly ordered arrays. Importantly, the dual buckle\u2010tongue\u2010latch interlocking mechanism between adjacent nanotubes stabilizes the ordered arrangement of the nanotubes through synergistic B\u2190N coordination and \u03c0\u2013\u03c0 stacking. Given these advantages,\n                    <jats:bold>CityU\u201056<\/jats:bold>\n                    has been demonstrated to serve as an artificial solid electrolyte interphase (ASEI) layer for lithium metal anodes, which significantly enhanced the stability and long\u2010term cycling performance of the as\u2010fabricated batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.202517238","type":"journal-article","created":{"date-parts":[[2025,9,30]],"date-time":"2025-09-30T08:17:35Z","timestamp":1759220255000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Interlocking Organic Nanotubes into a Three\u2010Dimensional Framework: Synthesis, Crystal Structure with Dual\u2010Buckle Configuration, and Application in Stabilizing Lithium Metal Anode"],"prefix":"10.1002","volume":"64","author":[{"given":"Zihao","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Tat Chee Avenue Kowloon Tong Hong Kong SAR P. 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