{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T15:47:39Z","timestamp":1792684059407,"version":"4.5.0"},"reference-count":67,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2025,12,18]],"date-time":"2025-12-18T00:00:00Z","timestamp":1766016000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,12,18]],"date-time":"2025-12-18T00:00:00Z","timestamp":1766016000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFA1500014"],"award-info":[{"award-number":["2023YFA1500014"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018594","name":"Central University Basic Research Fund of China","doi-asserted-by":"publisher","award":["GK202506033"],"award-info":[{"award-number":["GK202506033"]}],"id":[{"id":"10.13039\/501100018594","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22308204"],"award-info":[{"award-number":["22308204"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22421001"],"award-info":[{"award-number":["22421001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22132007"],"award-info":[{"award-number":["22132007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2025T180321"],"award-info":[{"award-number":["2025T180321"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M761894"],"award-info":[{"award-number":["2024M761894"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,2,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The microenvironment of single\u2010atom active sites plays a pivotal role in determining the activity and selectivity of the CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR). Herein, we report a highly efficient single\u2010atom catalyst, Co\u2010DABT\u2010COF, featuring Co(II)\u2010bithiazole N motifs that achieve exceptional CO\n                    <jats:sub>2<\/jats:sub>\n                    photoreduction performance (16.4\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 96% selectivity) under visible light irradiation in the presence of\u00a0a photosensitizer and a sacrificial agent. Through isoreticular design maintaining identical Co\u2010N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    primary coordination, Co\u2010DABT\u2010COF exhibits 2.8\u2010fold higher activity than its bipyridine analogue Co\u2010Bpy\u2010COF with Co(II)\u2010bipyridine N motifs (5.8\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Systematic characterization reveals the 2,2\u2032\u2010bithiazole ligand significantly enhances charge transfer efficiency and reduces the activation energy barrier for *COOH intermediate formation (0.79\u00a0eV versus 1.14\u00a0eV). Bader charge analysis demonstrates stronger electron donation from Co sites to CO\n                    <jats:sub>2<\/jats:sub>\n                    (0.63 e for Co\u2010DABT\u2010COF versus 0.58 e for Co\u2010Bpy\u2010COF), facilitating CO\n                    <jats:sub>2<\/jats:sub>\n                    activation. This work demonstrates a ligand\u2010engineering strategy for precisely tuning the electronic structure of single\u2010atom active sites to achieve efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion.\n                  <\/jats:p>","DOI":"10.1002\/anie.202517289","type":"journal-article","created":{"date-parts":[[2025,12,19]],"date-time":"2025-12-19T05:37:32Z","timestamp":1766122652000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Boosting CO\n                    <sub>2<\/sub>\n                    Photoreduction via Ligand\u2010Engineered Single\u2010Atom Cobalt Sites in Covalent Organic Frameworks"],"prefix":"10.1002","volume":"65","author":[{"given":"Ying","family":"Xu","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Molecular Nanostructure and Nanotechnology Beijing National Laboratory for Molecular Sciences (BNLMS) Institute of Chemistry Chinese Academy of Sciences (CAS)  Beijing 100190 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Hao","family":"Zhao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Institute of New Concept Sensors and Molecular Materials, School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an 710119 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Wang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Molecular Nanostructure and Nanotechnology Beijing National Laboratory for Molecular Sciences (BNLMS) Institute of Chemistry Chinese Academy of Sciences (CAS)  Beijing 100190 P.R. China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinbo","family":"Ma","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Molecular Nanostructure and Nanotechnology Beijing National Laboratory for Molecular Sciences (BNLMS) Institute of Chemistry Chinese Academy of Sciences (CAS)  Beijing 100190 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haizhou","family":"Liu","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Molecular Nanostructure and Nanotechnology Beijing National Laboratory for Molecular Sciences (BNLMS) Institute of Chemistry Chinese Academy of Sciences (CAS)  Beijing 100190 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin\u2010Song","family":"Hu","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Molecular Nanostructure and Nanotechnology Beijing National Laboratory for Molecular Sciences (BNLMS) Institute of Chemistry Chinese Academy of Sciences (CAS)  Beijing 100190 P.R. China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huan","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical Engineering Shaanxi University of Science and Technology  Xi'an 710021 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1649-942X","authenticated-orcid":false,"given":"Dong","family":"Wang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Molecular Nanostructure and Nanotechnology Beijing National Laboratory for Molecular Sciences (BNLMS) Institute of Chemistry Chinese Academy of Sciences (CAS)  Beijing 100190 P.R. China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,18]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaw7515"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/inf2.12279"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215057"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.205"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2023.114086"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00230"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202215187"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.202300050"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b02756"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09060"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36779-4"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c11008"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401004"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202502131"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CC01297J"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105904"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b07294"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201811010"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.024.202404675"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2024.120035"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201004443\u20104"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201801410"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202007442"},{"key":"e_1_2_8_24_1","volume":"452","author":"Hasija V.","year":"2022","journal-title":"Chem. Rev."},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904291"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202416958"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415202"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialsau.2c00061"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118\u2010012\u20101162\u2010y"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/pat.622"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.200800180"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202510550"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1116\/6.0002667"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC01616H"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0020\u20101693(00)80566\u20106"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA00397K"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(23)64552-8"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167\u20102738(01)00725\u20101"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA08412G"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2025.111096"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07206"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c01642"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.024.202404171"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE04121B"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202101568"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42757-7"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja406074w"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202210789"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008180"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c04820"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202328"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8RA06043F"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2020.128712"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201704624"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501391"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300643"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.125299"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.3c04060"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b09502"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.05.033"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02997"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202110694"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03800K"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09705"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC01747G"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.152798"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2025.116078"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202517289","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202517289","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202517289","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T08:36:17Z","timestamp":1779438977000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202517289"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12,18]]},"references-count":67,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2026,2,2]]}},"alternative-id":["10.1002\/anie.202517289"],"URL":"https:\/\/doi.org\/10.1002\/anie.202517289","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12,18]]},"assertion":[{"value":"2025-08-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-11","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-18","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e17289"}}