{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T09:21:35Z","timestamp":1791710495577,"version":"4.3.4"},"reference-count":72,"publisher":"Wiley","issue":"52","license":[{"start":{"date-parts":[[2025,10,28]],"date-time":"2025-10-28T00:00:00Z","timestamp":1761609600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,10,28]],"date-time":"2025-10-28T00:00:00Z","timestamp":1761609600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2023A1515011677"],"award-info":[{"award-number":["2023A1515011677"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12175295"],"award-info":[{"award-number":["12175295"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12005285"],"award-info":[{"award-number":["12005285"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U1932118"],"award-info":[{"award-number":["U1932118"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M763441"],"award-info":[{"award-number":["2024M763441"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,12,22]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The rational molecular design of interfacial modifiers is critical for optimizing charge transport and defect passivation in wide\u2010bandgap (WBG) perovskite solar cells (PSCs). Herein, we introduce a novel multifunctional molecule, (\n                    <jats:italic>Z<\/jats:italic>\n                    )\u20104\u2010(2\u2010(4\u2010bromophenyl)\u20102\u2010cyanovinyl) phenylamine (BCPA), synthesized via Knoevenagel condensation reaction, featuring a highly polar architecture with a ground\u2010state dipole moment of 18.16 Debye, significantly exceeding that of the benchmark Me\u20104PACz (1.60 Debye). This pronounced polarity stems from a synergistic combination of an electropositive ammonium group (\u2500NH\n                    <jats:sub>3<\/jats:sub>\n                    \u207a) and electronegative cyano (\u2500CN) and bromine (\u2500Br) substituents, which collectively foster strong interfacial dipole\u2013substrate interactions. The \u2500CN moiety coordinates with Ni\u02e3\u207a in NiO\n                    <jats:sub>X<\/jats:sub>\n                    and Pb\n                    <jats:sup>2<\/jats:sup>\n                    \u207a in perovskites, effectively passivating electronic defects and modulating self\u2010assembled molecules (SAM) anchoring. Meanwhile, the \u2500NH\n                    <jats:sub>3<\/jats:sub>\n                    \u207a group forms stable bonds with perovskite lattice, modulating crystal growth kinetics, and improving interfacial contact. The Br atom ensures intrinsic compatibility with bromine\u2010rich wide\u2010bandgap perovskites. Notably, the rigid, planar structure of BCPA facilitates ordered SAM packing via \u03c0\u2013\u03c0 interactions, enhancing interfacial charge extraction. BCPA\u2010modified hole transport layers significantly improve the buried perovskite\/substrate interface by reducing trap densities, enhancing crystallinity, and aligning energy levels. As a result, modified WBG PSCs realized a champion efficiency of 19.08% with reinforced durability. Furthermore, when applied in perovskite\u2010organic tandem configurations, the devices reach a remarkable PCE of 26.10%, highlighting the importance of interfacial modifier for next\u2010generation high\u2010efficiency photovoltaics.\n                  <\/jats:p>","DOI":"10.1002\/anie.202518169","type":"journal-article","created":{"date-parts":[[2025,10,28]],"date-time":"2025-10-28T15:20:48Z","timestamp":1761664848000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Knoevenagel Condensation Enables a High\u2010Dipole Interfacial Molecule for Efficient Wide\u2010Bandgap Perovskite and Tandem Photovoltaics"],"prefix":"10.1002","volume":"64","author":[{"given":"Xianfang","family":"Zhou","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Glass Materials  Wuhan 430070 China"},{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology  Wuhan 430070 China"},{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yonggui","family":"Sun","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baolei","family":"Tang","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"},{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Wang","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoman","family":"Ding","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoran","family":"Lin","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Tong","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoqing","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Critical Materials for Integrated Circuits Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huajun","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Glass Materials  Wuhan 430070 China"},{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology  Wuhan 430070 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Quanyao","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Glass Materials  Wuhan 430070 China"},{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology  Wuhan 430070 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunming","family":"Yang","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201204 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiwei","family":"Ren","sequence":"additional","affiliation":[{"name":"Advanced Materials and Electronics Laboratory Department of Electrical and Electronic Engineering The Hong Kong Polytechnic University  Hong Kong 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingjian","family":"Yuan","sequence":"additional","affiliation":[{"name":"College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gang","family":"Li","sequence":"additional","affiliation":[{"name":"Advanced Materials and Electronics Laboratory Department of Electrical and Electronic Engineering The Hong Kong Polytechnic University  Hong Kong 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5617-0998","authenticated-orcid":false,"given":"Hanlin","family":"Hu","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Postdoctoral Innovation Practice Base Shenzhen Polytechnic University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,10,28]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adr1334"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010024\u201008073\u2010w"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adv4280"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010025\u201001900\u20109"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201055523\u20100"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001791\u2010z"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010024\u201001531\u2010x"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010025\u201001725\u2010x"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504520"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001760\u20106"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad5845"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201059891\u2010z"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202511743"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001761\u20105"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061404\u2010x"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501764"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE00264H"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502391"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE05533K"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010025\u201009181\u2010x"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202405016"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214774"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507513"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202414125"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409689"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adj8858"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010024\u201007723\u20103"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502221"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416188"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201055653\u20105"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2024.101815"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418883"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311970"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202425605"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202400616"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202413104"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010017\u201005408\u20138"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202414128"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501210"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202501762"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202512660"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202501855"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201051760\u20135"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505876"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202404755"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c01564"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001613\u20108"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202316202"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2025.02.041"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c07357"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200417"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202505597"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE05319B"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502244"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202410601"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061563\u2010x"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202421547"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001742\u20138"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401476"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE01110H"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202304126"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adi4531"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202513416"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE02818F"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010025\u201001676\u20133"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/solr.202300495"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202420593"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423827"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402814"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311562"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416703"},{"key":"e_1_2_8_72_1","unstructured":"J.Huang GIWAXS\u2010Tools [Version 2.4.4] Program for Visualization of GIWAXS data https:\/\/gitee.com\/swordshinehjy\/giwaxs\u2010script(accessed on 14th Mar. 2025) 2025."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202518169","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202518169","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202518169","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T12:44:13Z","timestamp":1780317853000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202518169"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,28]]},"references-count":72,"journal-issue":{"issue":"52","published-print":{"date-parts":[[2025,12,22]]}},"alternative-id":["10.1002\/anie.202518169"],"URL":"https:\/\/doi.org\/10.1002\/anie.202518169","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,28]]},"assertion":[{"value":"2025-08-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-10-16","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-10-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e18169"}}