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Here, this work proposes a new concept of photothermal\u2010pyroelectric cascade catalysis (photopyroelectric catalysis) to circumvent the trade\u2010off for enhanced NIR\u2010II light\u2010driven catalytic efficiency, and develop a novel kind of multifunctional ZnS:Cu nanoparticles with a wide bandgap (2.7\u00a0eV) and high NIR\u2010II\u2010photothermal (52.4%) and pyroelectric efficiencies (0.44 mC m\n                    <jats:sup>\u22122<\/jats:sup>\n                    K\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), realizing high efficacy of NIR\u2010II light\u2010driven catalytical H\n                    <jats:sub>2<\/jats:sub>\n                    generation (8.7\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Under NIR\u2010II laser irradiation, intratumoral ZnS:Cu nanoparticles locally utilize thermal energy during both photothermal heating and natural cooling for pyroelectrocatalytic H\n                    <jats:sub>2<\/jats:sub>\n                    generation and oxidative depletion of intratumorally overexpressed glutathione, which induce tumor immunoactivation and ferroptosis, respectively, achieving high\u2010efficacy synergetic therapy of tumor. This work opens an avenue for exploiting NIR\u2010II light for efficient catalysis in the fields of both solar energy and catalytic medicine.\n                  <\/jats:p>","DOI":"10.1002\/anie.202518305","type":"journal-article","created":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T08:15:55Z","timestamp":1764749755000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["NIR\u2010II\u2010Photopyroelectric Catalysis for Immunoactivation\/Ferroptosis Combined Therapy of Tumor"],"prefix":"10.1002","volume":"65","author":[{"given":"Chao","family":"Xia","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Hydrogen Science &amp; Center of Hydrogen Science School of Materials Science and Engineering Shanghai Jiao Tong University  Shanghai 200240 China"},{"name":"Shenzhen Research Institute Shanghai Jiao Tong University  Shenzhen 518057 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Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingting","family":"Zeng","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Hydrogen Science &amp; Center of Hydrogen Science School of Materials Science and Engineering Shanghai Jiao Tong University  Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Danyang","family":"Chen","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Hydrogen Science &amp; Center of Hydrogen Science School of Materials Science and Engineering Shanghai Jiao Tong University  Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0689-8838","authenticated-orcid":false,"given":"Qianjun","family":"He","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Hydrogen Science &amp; Center of Hydrogen Science School of Materials Science and Engineering Shanghai Jiao 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