{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,14]],"date-time":"2026-06-14T22:15:06Z","timestamp":1781475306980,"version":"3.54.1"},"reference-count":58,"publisher":"Wiley","issue":"46","license":[{"start":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T00:00:00Z","timestamp":1759708800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T00:00:00Z","timestamp":1759708800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100020595","name":"National Science and Technology Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100020595","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,11,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Mineral nucleation is a fundamental process of paramount importance to various fields, including geology, biomineralization, and industrial manufacturing. Recently, studies on the biominerals of calcium carbonate and phosphate have revealed the presence of a dense liquid phase prior to the formation of an amorphous solid phase. Here, we show that liquid\u2013liquid phase separation occurs in a non\u2010aqueous solution where magnesium and calcium carbonates are dissolved in ethanol with excess triethylamine. The nanodroplets can be kinetically trapped by triethylamine. We found that molecular complexes of triethylamine, CO\n                    <jats:sub>2<\/jats:sub>\n                    , and ethanol molecules are in constant exchange with sizable carbonate clusters. We argue that nanodroplets comprising highly solvated carbonate clusters are the key entities in the nucleation process. Remarkably, the coalescence of the nanodroplets leads to the formation of a monolithic magnesium\u2010calcium carbonate containing two distinct domains with different Mg content.\n                  <\/jats:p>","DOI":"10.1002\/anie.202518706","type":"journal-article","created":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T07:13:24Z","timestamp":1759734804000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Formation of Monolithic Magnesium\u2013Calcium Carbonates Through Aggregation of Carbonate\u2010Cluster Nanodroplets"],"prefix":"10.1002","volume":"64","author":[{"given":"Shu\u2010Li","family":"Li","sequence":"first","affiliation":[{"name":"Department of Chemistry National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi\u2010Tan","family":"Lin","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hsi\u2010Ching","family":"Tseng","sequence":"additional","affiliation":[{"name":"Instrumentation Center National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan\u2010Jia","family":"Fan","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shing\u2010Jong","family":"Huang","sequence":"additional","affiliation":[{"name":"Instrumentation Center National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric Chung\u2010Yueh","family":"Yuan","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chun\u2010Yi David","family":"Lu","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5108-4166","authenticated-orcid":false,"given":"Jerry Chun Chung","family":"Chan","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Taiwan University  No. 1, Section 4 Roosevelt Road Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,10,6]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1093\/oso\/9780195049770.001.0001"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0248(98)00002-5"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0248(99)00749-6"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200306565"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/b701450c"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr800443h"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja800984y"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0nr00761g"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230915"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60451A"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.201600076"},{"key":"e_1_2_8_12_1","first-page":"1","author":"Jin B.","year":"2024","journal-title":"Nat. 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