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Herein, we report a CoNC catalyst with in situ generated uniform metal\u2013acid pairs, which exhibits superior activity and selectivity significantly outperforming reported non\u2010noble and noble metal catalysts. Moreover, CoNC shows excellent cycling stability and broad substrate adaptability. Catalyst characterizations, kinetic and isotopic labeling studies reveal that CoNC can efficiently dissociate H\n                    <jats:sub>2<\/jats:sub>\n                    to form H\n                    <jats:sup>+<\/jats:sup>\n                    \u2013N\u2013Co\u2013H\n                    <jats:sup>\u2212<\/jats:sup>\n                    , and easily adsorb and activate H\n                    <jats:sub>2<\/jats:sub>\n                    O for OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    exchange to form H\n                    <jats:sup>+<\/jats:sup>\n                    \u2013N\u2013Co\u2013OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    , producing abundant Br\u00f8nsted acid sites that then generate uniform metal\u2013acid pairs. The H\n                    <jats:sub>2<\/jats:sub>\n                    activation on the Co site enables the furfural hydrogenation to furfuryl alcohol, and the in situ generated acid sites catalyze the subsequent ring\u2010opening rearrangement. Moreover, the metal\u2013acid pairs effectively suppress undesired side reactions such as over\u2010hydrogenation and polymerization. This work provides a new class of metal\u2013acid bifunctional catalyst and expands the application of M\u2010NC catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202518751","type":"journal-article","created":{"date-parts":[[2025,11,26]],"date-time":"2025-11-26T12:31:42Z","timestamp":1764160302000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Hydrogenation Rearrangement of Furan Compounds to Cyclopentanones Catalyzed by CoNC with In Situ\u2010Generated Uniform Metal\u2013Acid Pairs"],"prefix":"10.1002","volume":"65","author":[{"given":"Zhensheng","family":"Shen","sequence":"first","affiliation":[{"name":"Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kang","family":"Xue","sequence":"additional","affiliation":[{"name":"Key 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