{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T02:33:41Z","timestamp":1787711621463,"version":"build-2784847793"},"reference-count":31,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,11,11]],"date-time":"2025-11-11T00:00:00Z","timestamp":1762819200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52176185"],"award-info":[{"award-number":["52176185"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52472093"],"award-info":[{"award-number":["52472093"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22379127"],"award-info":[{"award-number":["22379127"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52472127"],"award-info":[{"award-number":["52472127"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["W2441017"],"award-info":[{"award-number":["W2441017"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB3506300"],"award-info":[{"award-number":["2022YFB3506300"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,1,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The Cu cathode has great potential due to its low cost and high capacity. However, the limited ionic conductivity of the electrolyte for Cu ions and poor solubility of Cu species severely hinder the rapid development of Li\u2013Cu batteries. Herein, we synthesized a Cu\n                    <jats:sup>+<\/jats:sup>\n                    halide solid electrolyte (Cu\n                    <jats:sub>2<\/jats:sub>\n                    ZrCl\n                    <jats:sub>6<\/jats:sub>\n                    , CZC) by mechanochemical method, which exhibited a high room\u2010temperature Cu\n                    <jats:sup>+<\/jats:sup>\n                    conductivity (about 14 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and high solubility of Cu species. The Cu||CZC||Cu symmetric battery demonstrated the ability to maintain stable Cu\n                    <jats:sup>+<\/jats:sup>\n                    plating\/stripping over 1000 h at 0.1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . We further constructed a model of the synergistic migration and ion exchange of Cu\n                    <jats:sup>+<\/jats:sup>\n                    and Li\n                    <jats:sup>+<\/jats:sup>\n                    in CZC and Li\n                    <jats:sub>2<\/jats:sub>\n                    ZrCl\n                    <jats:sub>6<\/jats:sub>\n                    electrolytes. Based on this, we assembled the first all\u2010solid\u2010state lithium\u2013copper battery (ASSLCB), which delivered a high reversible specific capacity of 360 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    (1.7\u20133.8\u00a0V versus Li\u207a\/Li, at 37\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and exhibited outstanding cycling performance across 50 cycles at a current of 62.5\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Additionally, we designed a cathode\u2010free ASSLCB, utilizing aluminum foil as the current collector to demonstrate the deposition and dissolution of pure copper metal. This study provides a new design concept for Cu\n                    <jats:sup>+<\/jats:sup>\n                    conductors and lays a foundation for the future research of ASSLCBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202518966","type":"journal-article","created":{"date-parts":[[2025,11,11]],"date-time":"2025-11-11T08:30:52Z","timestamp":1762849852000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["An All\u2010Solid\u2010State Li\u2013Cu Battery via Cuprous\/Lithium\u2010Ion Halide Solid Electrolyte"],"prefix":"10.1002","volume":"65","author":[{"given":"Yueyue","family":"Wang","sequence":"first","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"},{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"},{"name":"National Power Battery Innovation Center GRINM Group Co. Ltd. General Research Institute for Nonferrous Metals  Beijing 100088 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Limin","family":"Wang","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"},{"name":"State Key Laboratory of Nonferrous Metals and Processes GRINM Group Co., Ltd. GRIMAT Engineering Institute Co., Ltd. General Research Institute for Nonferrous Metals  Beijing 100088 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolong","family":"Yan","sequence":"additional","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"},{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Xu","sequence":"additional","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"},{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Ningbo Key Laboratory of All\u2010Solid\u2010State Battery Zhejiang Key Laboratory of All\u2010Solid\u2010State Battery Eastern Institute of Technology  Ningbo Zhejiang 315200 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangzhen","family":"Zhu","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Ningbo Key Laboratory of All\u2010Solid\u2010State Battery Zhejiang Key Laboratory of All\u2010Solid\u2010State Battery Eastern Institute of Technology  Ningbo Zhejiang 315200 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanlong","family":"Wu","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"},{"name":"National Power Battery Innovation Center GRINM Group Co. Ltd. General Research Institute for Nonferrous Metals  Beijing 100088 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Han","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"},{"name":"National Power Battery Innovation Center GRINM Group Co. Ltd. General Research Institute for Nonferrous Metals  Beijing 100088 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changtai","family":"Zhao","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Congying","family":"Fang","sequence":"additional","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaokang","family":"Tan","sequence":"additional","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengying","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yinzhuang","family":"Fang","sequence":"additional","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingying","family":"Jiang","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biwei","family":"Xiao","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6713-2997","authenticated-orcid":false,"given":"Xiaona","family":"Li","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Ningbo Key Laboratory of All\u2010Solid\u2010State Battery Zhejiang Key Laboratory of All\u2010Solid\u2010State Battery Eastern Institute of Technology  Ningbo Zhejiang 315200 P.R. China"},{"name":"Ningbo Institute of Digital Twin  Ningbo Zhejiang 315200 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianwen","family":"Liang","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Mei","sequence":"additional","affiliation":[{"name":"College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,11,11]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202105577"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1198591"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.13"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201900151"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abb1342"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201020331\u20109"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2020.12.012"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c06884"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3091438"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2019.113615"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2020.227873"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c11181"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2018.12.064"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202214117"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2009.07.031"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12395"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2018.09.064"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212191"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adj8171"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306433"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201024697\u20102"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.01.026"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.vacuum.2021.110742"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040\u20106031(85)85553\u20102"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167\u20102738(94)90264\u2010X"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/0254\u20100584(89)90017\u20105"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201051710\u20101"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0925\u20108388(02)00230\u2010X"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2052252517010211"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2052520618015718"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c03893"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202518966","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,1,3]],"date-time":"2026-01-03T06:32:31Z","timestamp":1767421951000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202518966"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,11]]},"references-count":31,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2026,1,2]]}},"alternative-id":["10.1002\/anie.202518966"],"URL":"https:\/\/doi.org\/10.1002\/anie.202518966","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,11]]},"assertion":[{"value":"2025-08-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-02","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e18966"}}