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Industrial N\n                    <jats:sub>2<\/jats:sub>\n                    fixation is energy\u2010intensive and exacerbates carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) emissions, while high concentration of atmospheric CO\n                    <jats:sub>2<\/jats:sub>\n                    urgently requires scalable mitigation strategies. In this study, we report that simultaneous spontaneous activation of N\n                    <jats:sub>2<\/jats:sub>\n                    and CO\n                    <jats:sub>2<\/jats:sub>\n                    under ambient conditions in microdroplets, producing ammonium (NH\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    ), nitrite (NO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ), and formate (HCO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ), as confirmed by isotopic labelling experiments and theoretical calculations. This can clarify the doubts about environmental ammonia pollution in microdroplets. The activation of N\n                    <jats:sub>2<\/jats:sub>\n                    and CO\n                    <jats:sub>2<\/jats:sub>\n                    exhibits a synergistic enhancement effect in microdroplets. Mechanistic investigation reveals novel pathways involving the CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010facilitated N\n                    <jats:sub>2<\/jats:sub>\n                    fixation and the oxygen radical (\n                    <jats:sup>\u2022<\/jats:sup>\n                    O)\u2010mediated N\n                    <jats:sub>2<\/jats:sub>\n                    fixation. This discovery offers a sustainable pathway for green N\n                    <jats:sub>2<\/jats:sub>\n                    fixation and atmospheric CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization, and offers insights into the potential formation pathway of HONO in the atmosphere.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519068","type":"journal-article","created":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T06:13:28Z","timestamp":1764051208000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Synergistically Activating N\n                    <sub>2<\/sub>\n                    and CO\n                    <sub>2<\/sub>\n                    at Water Microdroplet Interfaces"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7905-4866","authenticated-orcid":false,"given":"Zaifa","family":"Shi","sequence":"first","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"},{"name":"State Key Laboratory of Environmental and Biological Analysis Hong Kong Baptist University  Hong Kong SAR 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Nie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zuo\u2010Chang","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas Ka\u2010Yam","family":"Lam","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Environmental and Biological Analysis Hong Kong Baptist University  Hong Kong SAR 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianing","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Environmental and Biological Analysis Hong Kong Baptist University  Hong Kong SAR 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Environmental and Biological Analysis Hong Kong Baptist University  Hong Kong SAR 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunkai","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"},{"name":"State Key Laboratory of Environmental and Biological Analysis Hong Kong Baptist University  Hong Kong SAR 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cunhao","family":"Cui","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haotian","family":"Ying","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianing","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Cai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou Fujian 350108 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingjie","family":"Zeng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanyan","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface College of Chemistry and Chemical Engineering Xiamen University  Xiamen Fujian 361005 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