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In resource molecules conversion (e.g., CO\n                    <jats:sub>2<\/jats:sub>\n                    and NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ), electrolytes serve multiple roles as reaction media, proton donors, and mass\u2010transport carriers, with their composition and physicochemical properties exerting a significant influence on reaction pathways, intermediate stability, and product selectivity. Most research endeavors have predominantly concentrated on catalyst design, often oversimplifying electrolytes as inert backgrounds. This minireview proposes a classification framework for electrolyte effects into short\u2010, medium\u2010, and long\u2010range interactions, highlighting their active regulatory roles at electrified interfaces. A comprehensive overview is provided of recent advancements in methodologies for investigating solvent effects, accompanied by an in\u2010depth analysis of representative electrocatalytic systems. This analysis elucidates how the composition of electrolytes influences molecular\u2010level elementary reaction steps, the dynamic reorganization and equilibrium of the interfacial microenvironment, as well as macroscopic catalytic performance, through a variety of distinct mechanisms. Finally, the key challenges and opportunities are also discussed, emphasizing electrolyte engineering as a strategic tool to reshape reaction environments and accelerate the practical deployment of electrocatalytic technologies.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519095","type":"journal-article","created":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T09:38:22Z","timestamp":1770370702000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Electrolyte\u2010Regulated Conversion of Small Resource Molecules"],"prefix":"10.1002","volume":"65","author":[{"given":"Limin","family":"Wu","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing 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