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Herein, a biomimetic NO capture\u2010activation\u2010conversion strategy was firstly formulated by encapsulating N\u2010acetylcysteine (\n                    <jats:bold>NAC<\/jats:bold>\n                    ) within a nicotinamide adenine dinucleotide (NADH) mimic\u2010containing coordination capsule, enabling efficiently NH\n                    <jats:sub>3<\/jats:sub>\n                    electrosynthesis. The installed NADH mimics onto the capsule interacted with the highly reactive NO\u2010adduct generated from\n                    <jats:bold>NAC<\/jats:bold>\n                    within the microenvironment akin to the pocket of enzyme, facilitating intramolecular hydride transfer of the substrate\u2010involving clathrate, accompanied by the formation of oxidated NAD\n                    <jats:sup>+<\/jats:sup>\n                    mimics. Subsequently, the cobalt\u2010based coordination capsule consecutively reserved\n                    <jats:italic>e<\/jats:italic>\n                    <jats:sup>\u2212<\/jats:sup>\n                    from cathode while donating 2\n                    <jats:italic>e<\/jats:italic>\n                    <jats:sup>\u2212<\/jats:sup>\n                    to the NAD\n                    <jats:sup>+<\/jats:sup>\n                    mimic simultaneously for active cofactor recovered and recycle. This coordination capsule\u2010mediated biomimetic system exhibited enzymatic kinetics following the Michaelis\u2013Menten mechanism in the electrochemical NO reduction and realized almost 100% Faraday efficiency at potentials below \u22120.2 V\n                    <jats:sub>RHE<\/jats:sub>\n                    with a substantial NH\n                    <jats:sub>3<\/jats:sub>\n                    yield rate of 121.6 \u00b5mol\u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at \u22120.3 V\n                    <jats:sub>RHE<\/jats:sub>\n                    , ranking among the optimal electrocatalytic NO performance ever achieved, offering an attractive avenue toward renewable electricity\u2010driven nitrogen fixation exploiting bioinspired artificial catalyst.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519123","type":"journal-article","created":{"date-parts":[[2025,11,10]],"date-time":"2025-11-10T08:27:53Z","timestamp":1762763273000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["NADH Mimic\u2010Decorated Coordination Capsules for Biomimetic Capture of NO and Electrocatalytic Reduction to NH\n                    <sub>3<\/sub>"],"prefix":"10.1002","volume":"65","author":[{"given":"Huali","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Frontier Science Center for Smart Materials Dalian University of Technology  Dalian 116024 P.R. 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