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Herein, we report\n                    <jats:bold>HOF\u2010FJU\u2010112a<\/jats:bold>\n                    , a flexible HOF material constructed from self\u2010assembled \u03c0\u2010pillars with suitable and adaptive one\u2010dimensional channels (3.6\u00a0\u00d7\u00a06.0\u00a0\u00c5), for thermodynamic and kinetic separation of Bz, CHE, and CHA ternary mixture. Specifically,\n                    <jats:bold>HOF\u2010FJU\u2010112a<\/jats:bold>\n                    is capable of thermodynamically separating Bz\/CHA and CHE\/CHA, while kinetically separating Bz\/CHE, simultaneously leading to a complete separation of the Bz\/CHE\/CHA ternary mixture. Breakthrough and elution experiments confirm efficient binary and ternary separation, including complete resolution of Bz\/CHE\/CHA mixtures into three pure components (99.9%) in one single column, with the outstanding breakthrough yield. This study demonstrates a new design paradigm for multifunctional HOFs and affirms their promise in challenging C6 hydrocarbon separations.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519313","type":"journal-article","created":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T08:06:32Z","timestamp":1764749192000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Thermodynamic and Kinetic Separation Within a Flexible Hydrogen Bonded Organic Framework for Ternary Benzene\/Cyclohexene\/Cyclohexane Mixture"],"prefix":"10.1002","volume":"65","author":[{"given":"Wuji","family":"Wei","sequence":"first","affiliation":[{"name":"Fujian Provincial Key Laboratory of Polymer Materials College of Chemistry and Materials Science Fujian Normal University Fuzhou  Fuzhou Fujian 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Science Zhejiang Normal University Zhejiang  Jinhua Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhangjing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Fujian Provincial Key Laboratory of Polymer Materials College of Chemistry and Materials Science Fujian Normal University Fuzhou  Fuzhou Fujian 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