{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T16:58:46Z","timestamp":1790701126574,"version":"4.1.0"},"reference-count":20,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T00:00:00Z","timestamp":1761436800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T00:00:00Z","timestamp":1761436800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,11,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    In a recent research article (doi.org\/10.1002\/anie.202507497), Chi, Huang, Qu et\u00a0al. described a multifunctional cathode for Zn\u2013I\n                    <jats:sub>2<\/jats:sub>\n                    batteries based on a\n                    <jats:italic>s<\/jats:italic>\n                    \u2010tetrazine ligand bearing two morpholine pendants, forming the active 2I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    @BMT complex. In addition to the lack of proper attribution for prior reports by other authors (doi.org\/10.1021\/acs.inorgchem.6b01138; doi.org\/10.1039\/c7dt00134g) regarding the design of this ligand as an anion receptor, its synthesis and its ability to form triiodide complexes, the article is affected by serious scientific\/technical flaws. The actual composition of the 2I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    @BMT complex was not established, and protonation of morpholine groups in aqueous media, essential to the formation of the triiodide complex, was overlooked, despite prior studies and crystallographic evidence. The 2:1 I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    :BMT ratio was investigated in chloroform using a Job plot, while a 1:1 stability constant was determined via UV\u2013vis titration in the same solvent. Both methods raise concerns, their results lack consistency and the extrapolation of data from chloroform to aqueous systems is not justified. Additionally, theoretical calculations yielded a highly positive binding energy, erroneously interpreted as indicative of complex stability, and a questionable complex structure featuring unconvincingly short anion\u2013tetrazine contacts. Nevertheless, functioning of reported cathode for Zn\u2013I\n                    <jats:sub>2<\/jats:sub>\n                    batteries is a notable outcome of the study.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519469","type":"journal-article","created":{"date-parts":[[2025,10,27]],"date-time":"2025-10-27T04:18:27Z","timestamp":1761538707000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Correspondence on \u201cConfinement of Polyiodides by Dual\u2010Functional Tetrazine Cathodes in Zn\u2013I\n                    <sub>2<\/sub>\n                    Batteries\u201d"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4602-0405","authenticated-orcid":false,"given":"Carla","family":"Bazzicalupi","sequence":"first","affiliation":[{"name":"Department of Chemistry \u201cUgo Schiff\u201d University of Florence, Via della Lastruccia 3  Sesto Fiorentino 50019 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1082-3911","authenticated-orcid":false,"given":"Antonio","family":"Bianchi","sequence":"additional","affiliation":[{"name":"Department of Chemistry \u201cUgo Schiff\u201d University of Florence, Via della Lastruccia 3  Sesto Fiorentino 50019 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manuel","family":"Melguizo","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Organic Chemistry University of Ja\u00e9n  Ja\u00e9n 23071 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3165-4456","authenticated-orcid":false,"given":"Fabio","family":"Pichierri","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Graduate School of Engineering Tohoku University  Sendai 980\u20108579 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9780-7542","authenticated-orcid":false,"given":"Matteo","family":"Savastano","sequence":"additional","affiliation":[{"name":"Department for the Promotion of Human Science and Quality of Life University San Raffaele Roma via di Val Cannuta 247 Rome 00166 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,10,26]]},"reference":[{"key":"e_1_2_4_1_1","volume-title":"Anion Coordination Chemistry","author":"Bowman\u2010James K.","year":"2012"},{"key":"e_1_2_4_2_1","volume-title":"Supramolecular Chemistry of Anions","author":"Bianchi A."},{"key":"e_1_2_4_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/9781847552471"},{"key":"e_1_2_4_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.10.029"},{"key":"e_1_2_4_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.06.016"},{"key":"e_1_2_4_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01138"},{"key":"e_1_2_4_7_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules24122247"},{"key":"e_1_2_4_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT00134G"},{"key":"e_1_2_4_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT04430E"},{"key":"e_1_2_4_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2017.04.029"},{"key":"e_1_2_4_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8QO01152D"},{"key":"e_1_2_4_12_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules23030572"},{"key":"e_1_2_4_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2023.107330"},{"key":"e_1_2_4_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507497"},{"key":"e_1_2_4_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC03888C"},{"key":"e_1_2_4_16_1","volume-title":"Fundamental of Analytical Chemistry","author":"Skoog D. 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