{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,1]],"date-time":"2026-11-01T03:47:52Z","timestamp":1793504872054,"version":"4.5.0"},"reference-count":66,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T00:00:00Z","timestamp":1762041600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52070100"],"award-info":[{"award-number":["52070100"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52200058"],"award-info":[{"award-number":["52200058"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22505167"],"award-info":[{"award-number":["22505167"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20220380"],"award-info":[{"award-number":["BK20220380"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018542","name":"Natural Science Foundation of Sichuan Province","doi-asserted-by":"publisher","award":["2025ZNSFSC0903"],"award-info":[{"award-number":["2025ZNSFSC0903"]}],"id":[{"id":"10.13039\/501100018542","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,1,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic nitrate reduction reaction offers an effective route for ammonia synthesis and actual wastewater treatment. Despite some important achievements, the progress is still low than expected, especially in low\u2010concentration nitrate, mostly because of slow hydrogenation kinetics and interfering substances. In this work, we presented that, by engineering spin orbital orientation, a carbon\u2010encapsulated FeP\/Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    heterojunctions (FeP\/Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    @C) enabled ultrafast and stable NH\n                    <jats:sub>3<\/jats:sub>\n                    electrosynthesis from low\u2010concentration nitrate. In\u2010situ characterization and theoretical calculation confirmed that FeP\/Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    heterojunctions induced spin orbit splitting of Fe, resulting in electron transition from low spin to high spin. The resulted non\u2010degenerate orbitals caused the energy levels shift up and guided the electron migration from FeP to Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    , which thus activated additional 3d orbital electron states. This spin orbital orientation further optimized the chemisorption properties of nitrogen\u2010oxygen intermediates and H* spillover, thus accelerating hydrogenation kinetics for ultrafast NH\n                    <jats:sub>3<\/jats:sub>\n                    electrosynthesis. Meanwhile, FeP\/Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    @C electrocatalyst alleviated the phosphate poisoning of active metal sites during industrial wastewater treatment, demonstrating excellent anti\u2010interference capability and environmental sustainability for real application. This work by modulating the \u201ccharge\u2010spin\u2010orbit\u201d structure of active sites provided a new strategy for rational design of high\u2010performance electrocatalysts for various electrocatalytic reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519571","type":"journal-article","created":{"date-parts":[[2025,11,3]],"date-time":"2025-11-03T07:31:08Z","timestamp":1762155068000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Charge\u2010Spin\u2010Orbit Modulated Carbon\u2010Encapsulated FeP\/Fe\n                    <sub>3<\/sub>\n                    O\n                    <sub>4<\/sub>\n                    Heterojunctions for Ultrafast and Stable Conversion of Low\u2010Concentration Nitrate to Ammonia"],"prefix":"10.1002","volume":"65","author":[{"given":"Yu","family":"Ge","sequence":"first","affiliation":[{"name":"Jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing 210023 China"},{"name":"State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lizhi","family":"Sun","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology of Ministry of Education National and Local Joint Engineering Laboratory of Energy Plant Bio\u2010fuel Preparation and Utilization College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinbing","family":"Xu","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing 210023 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Utilization College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,11,2]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005158\u20102"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00222A"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5c00327"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.12.025"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2023.05.037"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001406\u20107"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44286\u2010025\u201000237\u20103"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202508982"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c05673"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402294"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058811\u20105"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319029"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00715H"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202503291"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE03443D"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413042"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504015"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202402767"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44286\u2010025\u201000240\u20108"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201050670\u2010w"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047025\u2010w"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010022\u201001121\u20104"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217337"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207305"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058940\u2010x"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202510665"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402294"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201044469\u20104"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201044587\u2010z"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504213"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504505"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE02132D"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c12965"},{"key":"e_1_2_7_34_1","first-page":"28214","volume":"146","author":"Zhang 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