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However, research on employing this method to introduce aryl\/alkenyl groups onto the benzene ring is rather limited, with constrained structural scopes. Here, biaryl skeletons are readily prepared by harnessing the insertion of benzyne into C\u2550S double bond of pyridine\u20102(1\n                    <jats:italic>H<\/jats:italic>\n                    )\u2010thiones, where a pyridyl and an arylthio or alkenylthio group are simultaneously introduced on the formal triple bond of a benzyne. It is worth noting that these compounds can not only be further derivatized into 1,2\u2010diarylbenzenes or 2\u2010alkenyl\u20101,1\u2032\u2010biaryls via desulfurization, but can also form various complexes with different metals through diverse coordination modes.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519628","type":"journal-article","created":{"date-parts":[[2025,11,27]],"date-time":"2025-11-27T11:43:42Z","timestamp":1764243822000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Construction of Biaryl Skeletons Initiated with Benzyne Insertion into C\u2550S Double Bond of Pyridine\u20102(1\n                    <i>H<\/i>\n                    )\u2010thiones"],"prefix":"10.1002","volume":"65","author":[{"given":"Long","family":"Long","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. 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