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However, the design involves a tradeoff between defect passivation and charge transport, as multi\u2010site passivation molecules always introduce a resistive barrier. Herein, we employ a triple\u2010site planar molecule, 3\u2010amino\u20104\u2010chlorobenzenesulfonic acid (3A4Cl\u2010BZS), as a multifunctional modifier that can concurrently suppress non\u2010radiative recombination and enhance electron transfer. Specifically, functionalizing the benzene ring with sulfonic acid (\u2010SO\n                    <jats:sub>3<\/jats:sub>\n                    H) and amino (\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    ) groups enhances the passivation of undercoordinated Pb\n                    <jats:sup>2+<\/jats:sup>\n                    and I\n                    <jats:sup>\u2212<\/jats:sup>\n                    defects via coordination and hydrogen bonding, respectively, and incorporating a chlorine group promotes the parallel adsorption on the perovskite surface. The parallel configuration, rather than vertical orientation, minimizes the distance between the active site and the perovskite defects, significantly boosting passivation efficacy and mitigating the resistive barrier. Consequently, 1.67\u00a0eV bandgap perovskite solar cells achieve a power conversion efficiency (PCE) of 23.55%. Furthermore, integrating this cell into perovskite\/silicon TSC yields a high voltage of over 2 volts and a PCE of 31.42% adopting a planar silicon sub\u2010cell. Remarkably, encapsulated tandem devices retain over 80% of their initial PCE after 1960 h of maximum power point tracking under 1\u2010sun illumination at 25 \u00b0C.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519659","type":"journal-article","created":{"date-parts":[[2025,11,3]],"date-time":"2025-11-03T07:28:07Z","timestamp":1762154887000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Modulating Adsorption Orientation of Multi\u2010Site Ligand Enables Perovskite\/Silicon Tandem Solar Cells with Voltage Exceeding 2\u00a0V"],"prefix":"10.1002","volume":"65","author":[{"given":"Huiping","family":"Feng","sequence":"first","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information Displays College of Materials Science and Engineering Huaqiao University  Xiamen 361021 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College of Materials Science and Engineering Huaqiao University  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of High\u2010Efficiency Solar Cell Equipment and Technology Gold Stone (Fujian) Energy Company Limited  Quanzhou 362005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yining","family":"Gu","sequence":"additional","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information Displays College of Materials Science and Engineering Huaqiao University  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xubin","family":"Yuan","sequence":"additional","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information Displays College of Materials Science and Engineering Huaqiao University  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zishuo","family":"Dong","sequence":"additional","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information Displays College of Materials Science and Engineering Huaqiao University  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qinghua","family":"Zeng","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of High\u2010Efficiency Solar Cell Equipment and Technology Gold Stone (Fujian) Energy Company Limited  Quanzhou 362005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiarong","family":"Huang","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of High\u2010Efficiency Solar Cell Equipment and Technology Gold Stone (Fujian) Energy Company Limited  Quanzhou 362005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yalian","family":"Weng","sequence":"additional","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information Displays College of Materials Science and Engineering Huaqiao University  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinxin","family":"Yang","sequence":"additional","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information Displays College of Materials Science and Engineering Huaqiao University  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengbo","family":"Tian","sequence":"additional","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced 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