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Presodiation can directly improve ICE, but the imprecise and slow process can lead to under\u2010 or oversodiation and the formation of thick and unstable byproducts. Here, we propose a high precision and fast presodiation by aryl\u2010sodium (Ar\u2013Na) compounds dissolved in tetrahydrofuran (THF) with controlled potential and Ar\u2013Na binding energy. Based on the thermodynamic driving force (redox potential) and ionic transfer kinetics (Ar\u2013Na binding strength), a dual\u2010descriptor design principle for presodiation agent is established. Phenanthrene\u2013sodium (Ph\u2013Na) with a moderate ionic binding energy of\u00a0\u2212\u00a00.92\u00a0eV and a matched redox potential of 0.24\u00a0V versus Na\u207a\/Na enables \u223c100% ICE within 60 s and facilitates the formation of an ultrathin inorganic\u2010rich SEI in the battery that enhances interfacial kinetics and cycling stability. The presodiated HC delivers a reversible capacity of 308.9 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and paired with a Na\n                    <jats:sub>3<\/jats:sub>\n                    V\n                    <jats:sub>2<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    (NVP) cathode exhibits 94.8% ICE, 99.2 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    discharge capacity, and 82.6% capacity retention after 350 cycles, demonstrating a scalable presodiation strategy for practical SIBs.\n                  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Higher Education Institutes Institute of Materials Research Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayi","family":"Li","sequence":"additional","affiliation":[{"name":"Shenzhen Key Laboratory for Graphene\u2010based Materials Key Laboratory of Electrocatalytic Materials and Green Hydrogen Technology of Guangdong Higher Education Institutes Institute of Materials Research Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufei","family":"Zhao","sequence":"additional","affiliation":[{"name":"Shenzhen Key Laboratory for Graphene\u2010based Materials Key Laboratory of Electrocatalytic Materials and Green Hydrogen Technology of Guangdong Higher Education Institutes Institute of Materials Research Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenghong","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Materials (MOE) School of Materials Science and Engineering Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junwei","family":"Han","sequence":"additional","affiliation":[{"name":"Research Center on Advanced Chemical Engineering and Energy Materials China University of Petroleum (East China)  Qingdao 266580 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0874-3477","authenticated-orcid":false,"given":"Wei","family":"Lv","sequence":"additional","affiliation":[{"name":"Shenzhen Key Laboratory for Graphene\u2010based Materials Key Laboratory of Electrocatalytic Materials and Green Hydrogen Technology of Guangdong Higher Education Institutes Institute of Materials Research Tsinghua Shenzhen 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