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Developing artificial systems with on\u2010off responsive chiral induction and transfer, and elucidating their mechanisms, is of paramount importance. Here, we report the first pair of chiral porous organic cage (\n                    <jats:italic>R\/S<\/jats:italic>\n                    \u2010\n                    <jats:bold>BA\u2010PAC<\/jats:bold>\n                    ) exhibiting unprecedented chiral afterglow in a film state, boosting a remarkable lifetime of\u00a01.2\u00a0s and a dissymmetry factor (\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>lum<\/jats:sub>\n                    ) of 0.001. Loading rhodamine B (RB) guest molecules enables multicolor afterglow ranging from green to red, achieving 88% energy transfer. Notably, the confined RB displays a pronounced mirror\u2010imaged circular dichroism signal, and the induced chirality of RB demonstrates completely reversible on\u2010off switching under water vapor\/thermal stimulation, which is extremely rare in covalent porous materials. Experimental and theoretical studies have shown that the distortion of the benzoic acid moiety in RB is caused by hydrogen\u2010bonding interactions between benzoic acid group and the\n                    <jats:bold>BA\u2010PAC<\/jats:bold>\n                    . This distortion disrupts the electric\u2010magnetic dipole moment orthogonality of RB, inducing its chirality. Furthermore, the reversible disruption and reconstruction of the host\u2013guest hydrogen\u2010bonding network induced by external stimuli is a key mechanism for dynamic chiral transfer. This study bridges chiral induction and stimuli response in porous cages, providing a versatile biomimetic platform for investigating molecular\u2010level dynamic chirality transfer.\n                  <\/jats:p>","DOI":"10.1002\/anie.202519866","type":"journal-article","created":{"date-parts":[[2026,1,17]],"date-time":"2026-01-17T06:21:08Z","timestamp":1768630868000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Dynamic H\u2010Bonding Mediates Stimuli\u2010Responsive Chiral Induction in Porous Aromatic Cages with Multicolor Chiral Afterglow"],"prefix":"10.1002","volume":"65","author":[{"given":"Li","family":"Chen","sequence":"first","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education National &amp; Local United Engineering Laboratory for Power Battery Institution Northeast Normal University  Changchun Jilin 130024 China"},{"name":"Department of Chemistry Faculty of Science Yanbian University  Yanji Jilin 133002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Changchun University of Technology  Changchun Jilin 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianzhu","family":"Jiang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education National &amp; Local United Engineering Laboratory for Power Battery Institution Northeast Normal University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junning","family":"Kou","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education National &amp; Local United Engineering Laboratory for Power Battery Institution Northeast Normal University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guogang","family":"Shan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education National &amp; Local United Engineering Laboratory for Power Battery Institution Northeast Normal University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangyan","family":"Sun","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Yanbian University  Yanji Jilin 133002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinlong","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education National &amp; Local United Engineering Laboratory for Power Battery Institution Northeast Normal University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongmin","family":"Su","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical Chemistry College of Chemistry Jilin University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chi\u2010Ming","family":"Che","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Synthetic Chemistry CAS\u2010HKU Joint Laboratory on New Materials Department of Chemistry The University of Hong Kong  Pokfulam Road Hong Kong SAR P.R. 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