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However, harsh reaction conditions, poor selectivity, practicability, and sustainability have always restricted its application. Electrochemical synthesis has been considered as a practical and environmentally friendly organic synthesis strategy via a tunable redox process. Hence, herein, an efficient electrochemical controllable divergent carboxylation and hydrocarboxylation of alkynes with CO\n                    <jats:sub>2<\/jats:sub>\n                    was achieved to overcome the limitation of traditional methods. Four kinds of arylpropiolic acid, cinnamic acid, fumaric acid, succinic acid, and their derivatives can be obtained with good selectivity by regulating substrates, solvents, and electrolytes. The method features broad substrate scope, divergent transformation with good selectivity, scalability, additional reducing agent\u2010, hydrogen donor\u2010, metal\u2010, and ligand\u2010free conditions, which offer novel insights into electrochemically driven CO\n                    <jats:sub>2<\/jats:sub>\n                    fixation and alkyne functionalization.\n                  <\/jats:p>","DOI":"10.1002\/anie.202520335","type":"journal-article","created":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T09:01:01Z","timestamp":1763370061000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Electrochemical Controllable Divergent Carboxylation and Hydrocarboxylation of Alkynes with CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"65","author":[{"given":"Haomin","family":"Chen","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources Key Laboratory of Oil and Gas Fine Chemicals Ministry of Education &amp; Xinjiang Uygur Autonomous Region Urumqi Key Laboratory of Green Catalysis and Synthesis Technology College of Chemistry Xinjiang University  Urumqi 830017 P. 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