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The halogen\u2010mediated indirect electrocatalytic ethylene oxidation reactions (EOR) offer an attractive strategy for C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    conversion while still challenging. In this work, we rationally designed a series of highly crystalline and stable metallophthalocyanine covalent organic frameworks (COFs) for EORs. Among these COFs, NiPc\u2010TABQ COF achieved maximum Faraday efficiency (FE) of 81.3% for 2\u2010chloroethanol, and CoPc\u2010TABQ COF demonstrated exceptional EOR activity with FE of 76.5% for 2\u2010bromoethanol, which showed one of the best performances among previous reports. More importantly, this process was capable of being driven by solar energy through photovoltaic (PV) integration and natural seawater as electrolyte and source of chlorine thus achieved the efficient chlorine\u2010mediated EOR. Furthermore, the yield ClCH\n                    <jats:sub>2<\/jats:sub>\n                    CH\n                    <jats:sub>2<\/jats:sub>\n                    OH and BrCH\n                    <jats:sub>2<\/jats:sub>\n                    CH\n                    <jats:sub>2<\/jats:sub>\n                    OH tandemly converted into higher value\u2010added chemicals including ethylene glycol and ethylene carbonate, achieving conversion rate of 70% and 90%, respectively. Mechanistic insights were elucidated through in situ experimental analyses and density functional theory (DFT) calculations confirmed the halogen\u2010mediated processes. This work firstly realized the efficient EOR by COFs, also achieved solar energy driven and seawater electrolyte based green electrocatalysis for the first time, demonstrating their great potential in sustainable chemistry.\n                  <\/jats:p>","DOI":"10.1002\/anie.202520607","type":"journal-article","created":{"date-parts":[[2025,12,4]],"date-time":"2025-12-04T06:53:15Z","timestamp":1764831195000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Efficient Solar\u2010Driven Electrocatalytic Halogen\u2010Mediated Ethylene Oxidation in Seawater by Metallophthalocyanine\u2010Based COFs"],"prefix":"10.1002","volume":"65","author":[{"given":"Han","family":"Zhang","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization School of Chemistry South China Normal University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yixin","family":"Ouyang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Jie","family":"Guo","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization School of Chemistry South China Normal University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization School of Chemistry South China Normal University  Guangzhou 510006 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