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Electrochemical ketone hydrogenation under ambient conditions offers an attractive approach to synthesize secondary alcohols, but this process is often hindered by base\u2010catalyzed self\u2010condensation, hydrogenolysis, and competitive hydrogen evolution reaction (HER). Herein, we demonstrate that Ru nanoparticles supported on commercial carbon black (Ru\n                    <jats:sub>NP<\/jats:sub>\n                    \/C) can enable efficient, selective, and stable electrochemical hydrogenation of a wide range of structurally diverse ketones to produce corresponding secondary alcohols under ambient conditions. Mechanistic investigations reveal that Ru\n                    <jats:sub>NP<\/jats:sub>\n                    \/C can simultaneously promote generation of reactive hydrogen species and adsorption of ketone molecules, facilitating rapid transfer of reactive hydrogen species to adsorbed ketone molecules, thereby enabling efficient secondary alcohols formation and suppressing HER. This work opens a green and sustainable pathway for ketone upgrading.\n                  <\/jats:p>","DOI":"10.1002\/anie.202520868","type":"journal-article","created":{"date-parts":[[2025,12,5]],"date-time":"2025-12-05T14:21:08Z","timestamp":1764944468000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Ruthenium\u2010Catalyzed Electrochemical Ketone Hydrogenation to Secondary Alcohols with High Activity and Selectivity Under Ambient Conditions"],"prefix":"10.1002","volume":"65","author":[{"given":"Xuan","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Environmental Science and Engineering School of Energy and Power Engineering Xi'an Jiaotong University  Xi'an 710072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cejun","family":"Hu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 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Science and Engineering School of Energy and Power Engineering Xi'an Jiaotong University  Xi'an 710072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuwan","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering School of Energy and Power Engineering Xi'an Jiaotong University  Xi'an 710072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shan","family":"Ren","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering School of Energy and Power Engineering Xi'an Jiaotong University  Xi'an 710072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bingqing","family":"Yao","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering National University of Singapore  Singapore 119077 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City University of Hong Kong  Hong Kong SAR 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6636-0496","authenticated-orcid":false,"given":"Xinzhe","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering School of Energy and Power Engineering Xi'an Jiaotong University  Xi'an 710072 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