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Recently, luminescent coinage metal clusters exhibiting novel photophysical properties, such as afterglow emission, circularly polarized luminescence, near\u2010infrared luminescence, and x\u2010ray excited luminescence, have been successively reported, attracting significant research attention. In this work, the first photo\u2010responsive luminescent silver cluster (\n                    <jats:bold>\n                      Ag\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    ) was reported, whose phosphorescence can be activated through UV light irradiation in crystal state. Mechanism study revealed that the photo\u2010response of\n                    <jats:bold>\n                      Ag\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    was attributed to the photo\u2010induced oxygen scavenging by methanol within the lattice, which relieved the quenching of the phosphorescence of the metal cluster, leading to a \u201cturn\u2010on\u201d response. Due to its reversible photoactive luminescent properties in the solid state and excellent stability, a specialized photo\u2010responsive ink for three\u2010dimensional printing was developed based on\n                    <jats:bold>\n                      Ag\n                      <jats:sub>8<\/jats:sub>\n                    <\/jats:bold>\n                    . This study expands the range of luminescent coinage metal clusters and offers a novel strategy for the development of coinage metal cluster\u2010based stimuli\u2010responsive materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202521059","type":"journal-article","created":{"date-parts":[[2025,12,13]],"date-time":"2025-12-13T14:23:04Z","timestamp":1765635784000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Photoactive Luminescence in a Silver Cluster Crystal"],"prefix":"10.1002","volume":"65","author":[{"given":"Jia\u2010Yin","family":"Wang","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou 450001 China"},{"name":"Key Laboratory for Special Functional Materials of Ministry of Education School of Nanoscience and Materials Engineering Henan University  Kaifeng 475004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying\u2010Ying","family":"Lei","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Wang","family":"Yuan","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Li","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6728-0559","authenticated-orcid":false,"given":"Shuang\u2010Quan","family":"Zang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,13]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00769"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2718"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.679"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00703"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00896"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar200331z"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202508578"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010024\u201000741\u20107"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317597"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417934"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aay0107"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057209\u20107"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01393E"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00633H"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00800K"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00835"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.70140"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202309073"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.3c00563"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503457"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.475"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500481"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423787"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2025.102456"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c03721"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2023.100123"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac990193c"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010024\u201056237\u20105"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064202\u20107"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010024\u201000704\u2010y"},{"key":"e_1_2_5_31_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adk6628"},{"key":"e_1_2_5_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202421656"},{"key":"e_1_2_5_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202308194"},{"key":"e_1_2_5_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010024\u201001538\u20104"},{"key":"e_1_2_5_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003160"},{"key":"e_1_2_5_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424669"},{"key":"e_1_2_5_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2024.141583"},{"key":"e_1_2_5_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2016.11.093"},{"key":"e_1_2_5_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/1010\u20106030(93)80117\u2010R"},{"key":"e_1_2_5_40_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwab216"},{"key":"e_1_2_5_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_2_5_42_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0216272"},{"key":"e_1_2_5_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201005223\u20103"}],"container-title":["Angewandte 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