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However, designing efficient electrocatalysts to promote the electrocatalytic C\u2500N coupling process and achieve efficient urea production remains a challenge. Here, we design a copper (Cu)\u2010based coordination polymer catalyst, which can achieve the dual function of promoting C\u2500N coupling and protonation through sulfur (S)\u2010coordinated adjacent Cu sites. Through the unique Continuous Coupling Mechanism (CCM) of low Gibbs free energy of reaction intermediates (*CO\n                    <jats:sub>2\u00a0<\/jats:sub>\n                    +\u00a0*NO to *CO\n                    <jats:sub>2<\/jats:sub>\n                    NO to *ONCO\n                    <jats:sub>2<\/jats:sub>\n                    NO), the resulting catalyst achieved ultra\u2010high Faradaic efficiency (FE) (84.9\u00a0\u00b1\u00a03.1%) and production rate (0.34\u00a0\u00b1\u00a00.012\u00a0mol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Moreover, the FE and production rate of urea did not change noticeably during at least 90 cycles of testing.\n                  <\/jats:p>","DOI":"10.1002\/anie.202521363","type":"journal-article","created":{"date-parts":[[2025,12,19]],"date-time":"2025-12-19T05:41:16Z","timestamp":1766122876000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Continuous Coupling Mechanism for High Rate Electrosynthesis of Urea on Sulfur\u2010Coordinated Adjacent Copper Sites"],"prefix":"10.1002","volume":"65","author":[{"given":"Xiao","family":"Chen","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chenjia Town, Chongming District Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuaiqiang","family":"Jia","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chenjia Town, Chongming District Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianxin","family":"Zhai","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chenjia Town, Chongming District Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiapeng","family":"Jiao","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chenjia Town, Chongming District Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengke","family":"Dong","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chenjia Town, Chongming District Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"Xue","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chenjia Town, Chongming District Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhanghui","family":"Xia","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chenjia Town, Chongming District Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting","family":"Deng","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; 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