{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T02:09:19Z","timestamp":1790129359725,"version":"4.0.1"},"reference-count":44,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T00:00:00Z","timestamp":1768780800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T00:00:00Z","timestamp":1768780800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100002855","name":"Ministry of Science and Technology of the People's Republic of China","doi-asserted-by":"publisher","award":["2022YFA1203001"],"award-info":[{"award-number":["2022YFA1203001"]}],"id":[{"id":"10.13039\/501100002855","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002855","name":"Ministry of Science and Technology of the People's Republic of China","doi-asserted-by":"publisher","award":["2022YFA1203002"],"award-info":[{"award-number":["2022YFA1203002"]}],"id":[{"id":"10.13039\/501100002855","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["T2321003"],"award-info":[{"award-number":["T2321003"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22335003"],"award-info":[{"award-number":["22335003"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22105045"],"award-info":[{"award-number":["22105045"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["224B2903"],"award-info":[{"award-number":["224B2903"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["21511104900"],"award-info":[{"award-number":["21511104900"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["20JC1414902"],"award-info":[{"award-number":["20JC1414902"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,2,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Solar\u2010driven conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    into value\u2010added products is promising for renewable energy storage and carbon neutrality. Although current photocatalysts demonstrate the capability to convert CO\n                    <jats:sub>2<\/jats:sub>\n                    into multiple carbon products including ethanol, their performance is limited by high C\u2500C coupling energy barrier and inefficient intermediate enrichment. Here we synthesize a cobalt\u2010backboned oligomer as an efficient photocatalyst to generate a record\u2010high ethanol production rate of 497\u00a0\u00b5mol\/(g\u00b7h) for CO\n                    <jats:sub>2<\/jats:sub>\n                    photoreduction. It also maintains high performance in cases with simulated industrial flue gas with \u223c15% CO\n                    <jats:sub>2<\/jats:sub>\n                    and a Martian\u2010like atmosphere with \u223c95% CO\n                    <jats:sub>2<\/jats:sub>\n                    . These properties stem from unique electronic modulation through metal\u2013metal bonding and intermolecular assembly for high\u2010activity reaction channels. This atomically precise cobalt\u2010backboned oligomer opens a new avenue for designing photocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202521378","type":"journal-article","created":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T05:55:48Z","timestamp":1768888548000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Cobalt\u2010Backboned Oligomer for Record Photocatalytic CO\n                    <sub>2<\/sub>\n                    Conversion to Ethanol"],"prefix":"10.1002","volume":"65","author":[{"given":"Yifeng","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Institute of Fiber Materials and Devices Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuya","family":"Hao","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials State Key Laboratory of Porous Materials for Separation and Conversion Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanruzhen","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Institute of Fiber Materials and Devices Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fuyao","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Institute of Fiber Materials and Devices Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingyi","family":"Pang","sequence":"additional","affiliation":[{"name":"Physics Department &amp; Shanghai Key Laboratory of Magnetic Resonance School of Physics and Electronic Science East China Normal University  Shanghai 200062 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuelu","family":"Wang","sequence":"additional","affiliation":[{"name":"Physics Department &amp; Shanghai Key Laboratory of Magnetic Resonance School of Physics and Electronic Science East China Normal University  Shanghai 200062 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Porous Materials for Separation and Conversion Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials MOE Key Laboratory of Computational Physical Sciences Research Center for Chemical Theory Department of Chemistry Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaiwen","family":"Zeng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Institute of Fiber Materials and Devices Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gengfeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials State Key Laboratory of Porous Materials for Separation and Conversion Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2142-2945","authenticated-orcid":false,"given":"Huisheng","family":"Peng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Institute of Fiber Materials and Devices Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,19]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1239176"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010021\u201004174\u2010y"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abc1226"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02714J"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2019.06.009"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NR02588D"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adq2791"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.06.033"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202201428"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE02643D"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature23016"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2025.101293"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423666"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202418427"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820\u2010023\u201001276\u20102"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310912"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2025.04.019"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216060"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502327"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/b515311e"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/b801115j"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5c00619"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0103142"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.comptc.2019.01.012"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja994051b"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202416358"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121359"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207222"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20102067(23)64642\u2010X"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmr.2013.11.009"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423859"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202513840"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20102067(23)64630\u20103"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506663"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE02449D"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c11842"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411000"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.153560"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE02643D"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208904"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.5194\/essd\u201017\u2010965\u20102025"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.06.001"},{"key":"e_1_2_7_43_1","volume-title":"NMR Spectroscopy: Basic Principles, Concepts and Applications in Chemistry","author":"G\u00fcnther H.","year":"2013"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.3390\/rs13173439"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202521378","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202521378","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202521378","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T22:37:55Z","timestamp":1773009475000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202521378"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,19]]},"references-count":44,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2026,2,23]]}},"alternative-id":["10.1002\/anie.202521378"],"URL":"https:\/\/doi.org\/10.1002\/anie.202521378","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,19]]},"assertion":[{"value":"2025-09-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e21378"}}